Synthesis and crystal structure of the first d–fheterodinuclear Dy(III)–Cu(II) cryptate

Qiu-Yun Chen; Qin-Hui Luo; Zhi-Lin Wang; Jiu-Tong Chen

doi:10.1039/A909926N

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Synthesis and crystal structure of the first d–f heterodinuclear Dy(iii)–Cu(ii) cryptate

Qiu-Yun Chen,^a Qin-Hui Luo,^a Zhi-Lin Wang^a and Jiu-Tong Chen^b

Author affiliations

^a Coordination Chemistry Institute and State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, P.R. China.
E-mail: qhluo@netra.nju.edu.cu

^b FuZhou State Key Laboratory of Structural Chemtry, FuZhou, P.R. China

Abstract

The heterodinuclear cryptate [DyCuL(DMF)](ClO₄)₂· MeCN [where L denotes the deprotonated anionic cryptand obtained by condensation of tris(2-aminoethyl)amine with 2,6-diformyl-4-chlorophenol] has been obtained by a stepwise method; the presence of copper(II) and dysprosium(III) in the cavity of the cryptand was evidenced by X-ray structure analysis and ESMS spectroscopy.

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Supplementary files

Crystal structure data TXT (27K)

Article information

DOI: https://doi.org/10.1039/A909926N
Article type: Communication
Submitted: 21 Dec 1999
Accepted: 03 May 2000
First published: 26 May 2000

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Chem. Commun., 2000, 1033-1034

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Synthesis and crystal structure of the first d–f heterodinuclear Dy(III)–Cu(II) cryptate

Q. Chen, Q. Luo, Z. Wang and J. Chen, Chem. Commun., 2000, 1033 DOI: 10.1039/A909926N

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