Issue 10, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Free radical chemistry. Part 11.1 Additions of cyclic and acyclic alcohols and diols to hexafluoropropene

Richard D. Chambers,*a   Patrick Diter,b   Stephen N. Dunn,a   Christopher Farren,a   Graham Sandford,*a   Andrei S. Batsanovc  and  Judith A. K. Howardc  

* Corresponding authors

a Department of Chemistry, University of Durham, South Road, Durham, UK

b SIRCOB, Universite de Versailles, 45 Ave des Etats Unis, Versailles, France

c Chemical Crystallography Unit, University of Durham, South Road, Durham, UK

Abstract

Peroxide and γ-ray initiated reactions of cyclic alcohols, and various cyclic and acyclic diols, with hexafluoropropene are described. Regiospecific additions are observed and structures follow from NMR data. X-Ray crystallography established the structures of some isomers. A variety of polyfluoroalkylated alkenes, dienes and aromatic building-blocks were derived from the polyfluoroalkylated alcohols.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/A909778C
Article type
Paper
Submitted
13 Dec 1999
Accepted
08 Mar 2000
First published
26 Apr 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 1639-1649

Permissions

Request permissions

Free radical chemistry. Part 11. Additions of cyclic and acyclic alcohols and diols to hexafluoropropene

R. D. Chambers, P. Diter, S. N. Dunn, C. Farren, G. Sandford, A. S. Batsanov and J. A. K. Howard, J. Chem. Soc., Perkin Trans. 1, 2000, 1639 DOI: 10.1039/A909778C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements