Issue 12, 1999
From the journal:

Journal of Materials Chemistry

Synthesis and characterization of a pipe-structure manganese vanadium oxide by hydrothermal reaction

Fan Zhang,   Peter Y. Zavalij  and  M. Stanley Whittingham  

Abstract

A novel manganese vanadium oxide has been synthesized using the hydrothermal reaction of vanadium(V) pentoxide with manganese(II) sulfate with an organic templating cation at 165 °C. The (Mn2+)6(Mn3+)1–2/3z- (OH)3(VO4)3[(VO4)1–2z(V2O7)z] (z = 0.2) phase has a hexagonal tunnel structure and space group P63mc. The cell parameters of this compound are a = 13.229(1) and c = 5.255(1) Å. This compound was also characterized by electron microprobe analysis, FTIR, TGA as well as electrochemically and reacted readily with lithium in electrochemical cells.

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Article information

DOI
https://doi.org/10.1039/A907465A
Article type
Paper

J. Mater. Chem., 1999,9, 3137-3140

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Synthesis and characterization of a pipe-structure manganese vanadium oxide by hydrothermal reaction

F. Zhang, P. Y. Zavalij and M. Stanley Whittingham, J. Mater. Chem., 1999, 9, 3137 DOI: 10.1039/A907465A

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