Issue 21, 1999
From the journal:

Chemical Communications

Facile, metal promoted, oxidation of η4-1,3-diphosphacyclobutadiene by water or methanol: synthesis of [MoCl(CO)(η4-1,3-P2C2But2)(η5-L)] (L = C5H5, C5Me5) and [MoCl(CO){η3,λ3,λ5-PC2But2PH(OR)}(η5-L)] (L= C5H5,R = H, Me)

Andrew S. Weller,   Christopher D. Andrews,   Andrew D. Burrows,   Michael Green,   Jason M. Lynam,   Mary F. Mahon  and  Cameron Jones  

Abstract

The new complexes [MoCl(CO)(η4-1,3-P2C2But2)(η5-L)] (L = C5H5 1, C5Me5 2) are reported; facile oxidation of 1 with water or methanol affords a rare example of a mixed valence phosphaphosphonietinyl in [MoCl(CO){η3,λ3,λ5-PC2But2- PH(OR)}(η5-C5H5)] (R = H, Me), which has also been structurally characterised for R=H.

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Article information

DOI
https://doi.org/10.1039/A905240B
Article type
Paper

Chem. Commun., 1999, 2147-2148

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Facile, metal promoted, oxidation of η4-1,3-diphosphacyclobutadiene by water or methanol: synthesis of [MoCl(CO)(η4-1,3-P2C2But2)(η5-L)] (L = C5H5, C5Me5) and [MoCl(CO){η3,λ3,λ5-PC2But2PH(OR)}(η5-L)] (L= C5H5,R = H, Me)

A. S. Weller, C. D. Andrews, A. D. Burrows, M. Green, J. M. Lynam, M. F. Mahon and C. Jones, Chem. Commun., 1999, 2147 DOI: 10.1039/A905240B

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