Issue 18, 1999
From the journal:

Chemical Communications

Oxidation of methyl groups in the reaction of sulfur homopolyatomic cations with acetonitrile: formation and crystal structure of the novel trithietanylium ring

T. Stanley Cameron,   Andreas Decken,   Min Fang,   Jack Passmore,   Dale J. Wood  and  Simon Parsons  

Abstract

RCN (R = C6F5, Me) reacts with Sn(AsF6)2 (n = 4, 8) in liquid SO2 to give the corresponding 3,5-disubstituted-1,2,4 thiadiazoles, and also, in the MeCN case, the tricyclic trication 4 containing the trithietanylium -CSSS+ and 1,2,3-dithiazolium -CSSNCH+ rings formed by the oxidation of methyl groups by sulfur homopolyatomic cations.

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Article information

DOI
https://doi.org/10.1039/A904107I
Article type
Paper

Chem. Commun., 1999, 1801-1802

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Oxidation of methyl groups in the reaction of sulfur homopolyatomic cations with acetonitrile: formation and crystal structure of the novel trithietanylium ring

T. Stanley Cameron, A. Decken, M. Fang, J. Passmore, D. J. Wood and S. Parsons, Chem. Commun., 1999, 1801 DOI: 10.1039/A904107I

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