Styrene is readily converted to 2-phenylaziridine by salen manganese(V) nitrido complexes in the presence of Brønsted or Lewis acids such as F3CCO2H or BF3, the crystal structure of a chiral manganese nitrido complex that can perform asymmetric alkene aziridination has been determined.
C. Ho, T. Lau, H. Kwong and W. Wong, J. Chem. Soc., Dalton Trans., 1999, 2411 DOI: 10.1039/A903605I
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