Issue 7, 1999
From the journal:

Journal of the Chemical Society, Dalton Transactions

Novel Cu–Se clusters with Se–layer structures: [Cu32Se7(SenBu)18(PiPr3)6], [Cu50Se20(SetBu)10(PiPr3)10], [Cu73Se35(SePh)3(PiPr3)21], [Cu140Se70(PEt3)34] and [Cu140Se70(PEt3)36]

Nianyong Zhu  and  Dieter Fenske  

Abstract

The clusters [Cu32Se7(SenBu)18(PiPr3)6], [Cu50Se20(SetBu)10(PiPr3)10], [Cu73Se35(SePh)3(PiPr3)21], [Cu140Se70(PEt3)34] and [Cu140Se70(PEt3)36] were prepared from the reactions of CuCl, RSeSiMe3 and Se(SiMe3)2 (R = Ph, nBu or tBu) in the presence of phosphine ligands and their molecular structures were determined. The Se–Bu bond was cleaved more easily than the Se–Ph bond under the reaction conditions studied.

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Article information

DOI
https://doi.org/10.1039/A900021F
Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 1067-1076

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Novel Cu–Se clusters with Se–layer structures: [Cu32Se7(SenBu)18(PiPr3)6], [Cu50Se20(SetBu)10(PiPr3)10], [Cu73Se35(SePh)3(PiPr3)21], [Cu140Se70(PEt3)34] and [Cu140Se70(PEt3)36]

N. Zhu and D. Fenske, J. Chem. Soc., Dalton Trans., 1999, 1067 DOI: 10.1039/A900021F

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