Issue 20, 1998
From the journal:

Journal of the Chemical Society, Dalton Transactions

An unprecedented trinucleating bridging mode (µ3-η1∶η1∶η1) of a tris(pyrazolyl)borate ligand in a trinuclear silver(I) complex

Elizabeth R. Humphrey,   Nicholas C. Harden,   Leigh H. Rees,   John C. Jeffery,   Jon A. McCleverty  and  Michael D. Ward  

Abstract

The crystal structure of [Ag3(TpAn)2][ClO4], where TpAn is tris[3-(2-methoxyphenyl)pyrazol-1-yl]hydroborate, shows a unique trinucleating bridging coordination mode for the tris(pyrazolyl)borate: each of the two ligands coordinates one pyrazolyl donor to each of the three two-coordinate Ag(I) ions, affording a triangular complex in which each face is capped by a µ3-η1∶η1∶η1-tris(pyrazolyl)borate.

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Article information

DOI
https://doi.org/10.1039/A806333H
Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 3353-3354

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An unprecedented trinucleating bridging mode (µ3-η1∶η1∶η1) of a tris(pyrazolyl)borate ligand in a trinuclear silver(I) complex

E. R. Humphrey, N. C. Harden, L. H. Rees, J. C. Jeffery, J. A. McCleverty and M. D. Ward, J. Chem. Soc., Dalton Trans., 1998, 3353 DOI: 10.1039/A806333H

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