Issue 3, 1999
From the journal:

Journal of the Chemical Society, Dalton Transactions

Confinement of C60 in an extended saddle shaped nickel(II) macrocycle

Paul D. Croucher,   Peter J. Nichols  and  Colin L. Raston  

Abstract

Saddle shaped (5,14-dihydro-2,3,6,8,11,12,15,17-octamethyldibenzo[b,i ] [1,4,8,11]tetraazacyclotetradecine)nickel(II), Ni(OMTAA), acts as a divergent receptor molecule with C60 forming a 1∶1 complex in solution and in the solid state, isolated as [Ni(OMTAA)C60]·2CS2. The extended supramolecular array is based on linear chains of close contact C60 molecules [fullerene · · · fullerene centroids 10.03(1) and 10.04(1) Å], and linear chains of π-stacked alternating molecules of C60 and Ni(OMTAA) with adjacent chains running in opposite directions.

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DOI
https://doi.org/10.1039/A805893H
Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 279-284

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Confinement of C60 in an extended saddle shaped nickel(II) macrocycle

P. D. Croucher, P. J. Nichols and C. L. Raston, J. Chem. Soc., Dalton Trans., 1999, 279 DOI: 10.1039/A805893H

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