Issue 18, 1998
From the journal:

Journal of the Chemical Society, Dalton Transactions

Syntheses and structures of new copper(I) selenide clusters [Cu32Se16(PPh3)12], [Cu52Se26(PPh3)16] and [Cu72Se36(PPh3)20] †

Andreas Eichhöfer  and  Dieter Fenske  

Abstract

The reaction of Se(SiMe3)2 with copper(I) acetate in the presence of PPh3 yielded the new clusters [Cu32Se16(PPh3)12] 2, [Cu52Se26(PPh3)16] 3 and [Cu72Se36(PPh3)20] 4 depending on the conditions. The molecular structures of 2, 3 and 4 have been characterised by X-ray crystallography and compared with the known cluster [Cu146Se73(PPh3)30] 1 obtained from the same reaction under different conditions.

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Article information

DOI
https://doi.org/10.1039/A803675F
Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 2969-2972

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Syntheses and structures of new copper(I) selenide clusters [Cu32Se16(PPh3)12], [Cu52Se26(PPh3)16] and [Cu72Se36(PPh3)20] †

A. Eichhöfer and D. Fenske, J. Chem. Soc., Dalton Trans., 1998, 2969 DOI: 10.1039/A803675F

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