Issue 13, 1998
From the journal:

Journal of the Chemical Society, Dalton Transactions

Turning dihydrogen gas into a strong acid. Formation and reactions of the very acidic ruthenium dihydrogen complexes trans-[Ru(H2)(CNH){PPh2(CH2)nPPh2}2][O3SCF3]2 (n = 2 or 3)

Tina P. Fong,   Alan J. Lough,   Robert H. Morris,   Antonio Mezzetti,   Eliana Rocchini  and  Pierluigi Rigo  

Abstract

New, very acidic ruthenium dihydrogen complexes containing the hydrogen isocyanide ligand have been synthesised; when formed under 1 atm H2 they have been shown to spontaneously eliminate trifluoromethylsulfonic acid.

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Article information

DOI
https://doi.org/10.1039/A803256D
Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 2111-2114

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Turning dihydrogen gas into a strong acid. Formation and reactions of the very acidic ruthenium dihydrogen complexes trans-[Ru(H2)(CNH){PPh2(CH2)nPPh2}2][O3SCF3]2 (n = 2 or 3)

T. P. Fong, A. J. Lough, R. H. Morris, A. Mezzetti, E. Rocchini and P. Rigo, J. Chem. Soc., Dalton Trans., 1998, 2111 DOI: 10.1039/A803256D

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