Issue 15, 1998

Tl2Au4S3: x = 4/3 member of the series A2 – xAuxQ. Preparation and an analysis of its gold–gold bonding

Abstract

Tl2Au4S3 was synthesized by reacting gold with reactive fluxes of Tl2S and S; its crystal structure is characterised by sheets of buckled 16-membered rings of Au and S with short Au–Au contacts between the sheets; the Au–Au bonding has been analysed through high-level band structure calculations.

Article information

Article type
Paper

Chem. Commun., 1998, 1603-1604

Tl2Au4S3: x = 4/3 member of the series A2 – xAuxQ. Preparation and an analysis of its gold–gold bonding

S. Löken and C. Felser, Chem. Commun., 1998, 1603 DOI: 10.1039/A802571A

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