Issue 11, 1997

Copper(i) salt promoted homo-coupling reaction of organosilanes

Abstract

Alkenylfluorosilanes, phenylfluorosilanes or alkynylsilanes smoothly dimerize in the presence of a copper(I) salt in a polar solvent such as N,N-dimethylformamide (DMF) or dimethyl sulfoxide (DMSO) to give the 1,3-conjugated dienes, biphenyl or 1,3-conjugated diynes, respectively.

Article information

Article type
Paper

Chem. Commun., 1997, 1039-1040

Copper(i) salt promoted homo-coupling reaction of organosilanes

K. Ikegashira, Y. Nishihara, K. Hirabayashi, A. Mori and T. Hiyama, Chem. Commun., 1997, 1039 DOI: 10.1039/A701898C

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