Issue 2, 1995

Bis(η-cyclopentadienyl)imidomolybdenum compounds

Abstract

The mono(η-cyclopentadienyl)imide compounds [Mo(η-C5H4R)(NR′)Cl2](R, R′= H, R″; Me, Pri; Me, R″; or Pri, R″; R″= C6H3Me2-2,6) and the new bis(η-cyclopentadienyl)imide compounds [Mo(η-C5H4R)2(NR′)](R, R′= Me, But; H, But; H, Pri; H, Ph; H, R″; Me, Pri; Me, Ph; Me, R″; Pri, But; or Pri, R″), [Mo(η-C5H5)(η-C5H4Pri)(NBut)], [Mo(η3-C9H7)(η-C5H4Pri)(NBut)] and [Mo(η- C5H4Me)2Me(NBut)]X (X = I or BF4) have been prepared. The salt [Mo(η-C5H4Me)(PMe3)2(NBut)][C5H4Me] has also been prepared. The crystal structures of the latter and of [Mo(η-C5H5)2(NBut)] have been determined.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1995, 155-162

Bis(η-cyclopentadienyl)imidomolybdenum compounds

M. L. H. Green, P. C. Konidaris, D. M. Michaelidou and P. Mountford, J. Chem. Soc., Dalton Trans., 1995, 155 DOI: 10.1039/DT9950000155

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