Issue 35, 2023
From the journal:

Chemical Communications

Coaxial assembly of helical aromatic foldamers by metal coordination†

Albano Galan,a   Kristijan Lulic,b   Jingqi Wang,b   Barbara Wicher, ORCID logo d   Ivan Huc, ORCID logo ac   Jean Duhamelb  and  Victor Maurizot ORCID logo *a  

* Corresponding authors

a Université de Bordeaux, CNRS, Bordeaux Institut National Polytechnique, CBMN (UMR 5248), Institut Européen de Chimie Biologie, 2 Rue Escarpit, Pessac 33600, France
E-mail: victor.maurizot@u-bordeaux.fr

b Institute for Polymer Research, Waterloo Institute for Nanotechnology, Department of Chemistry, University of Waterloo, 200 University Avenue West, Waterloo, ON N2L 3G1, Canada
E-mail: jduhamel@uwaterloo.ca

c Department Pharmazie, Ludwig-Maximilians-Universität München, Butenandtstraße 5–13, Munich D-81377, Germany

d Department of Chemical Technology of Drugs, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan, Poland

Abstract

Deprotonation of acid-terminated helical aromatic foldamers with a mineral base in chlorinated solvents led to their dimerization through the coordination of a metal cation (Li+, Na+, K+, Ag+, or Hg2+) with the terminal carboxylate functions. This new ligation method was applied to oligomerize diacid-functionalized foldamers.

Graphical abstract: Coaxial assembly of helical aromatic foldamers by metal coordination

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Article information

DOI
https://doi.org/10.1039/D3CC00866E
Article type
Communication
Submitted
23 Feb 2023
Accepted
03 Apr 2023
First published
03 Apr 2023
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2023,59, 5253-5256

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Coaxial assembly of helical aromatic foldamers by metal coordination

A. Galan, K. Lulic, J. Wang, B. Wicher, I. Huc, J. Duhamel and V. Maurizot, Chem. Commun., 2023, 59, 5253 DOI: 10.1039/D3CC00866E

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