Issue 34, 2021

Facile synthesis of novel, known, and low-valent transition metal phosphates via reductive phosphatization

Abstract

Novel and known low-valent transition metal phosphates (TMPs) are accessible via a novel and facile pathway. The method allows syntheses of TMPs also with reduced oxidation states. The key feature of the new route is the reductive character of a hypophosphite salt melt, which acts as reaction medium and enables directing the oxidation state of the transition metal.

Graphical abstract: Facile synthesis of novel, known, and low-valent transition metal phosphates via reductive phosphatization

Supplementary files

Article information

Article type
Communication
Submitted
05 May 2021
Accepted
12 Aug 2021
First published
18 Aug 2021
This article is Open Access
Creative Commons BY license

J. Mater. Chem. A, 2021,9, 18247-18250

Facile synthesis of novel, known, and low-valent transition metal phosphates via reductive phosphatization

N. Stegmann, H. Petersen, C. Weidenthaler and W. Schmidt, J. Mater. Chem. A, 2021, 9, 18247 DOI: 10.1039/D1TA03782J

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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