Issue 39, 2020
From the journal:

New Journal of Chemistry

Stabilization and isolation of radical cation and dication salts of a tetrathiafulvalene derivative functionalized with amino groups†

Xiang Li,a   Yu-Han Liu,a   Guang-Zhou Zhua  and  Feng Gao ORCID logo *a  

* Corresponding authors

a School of Chemistry & Materials Science, Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou 221116, P. R. China
E-mail: gf2016@jsnu.edu.cn

Abstract

The radical cation and dication salts of a tetrathiafulvalene (TTF) derivative functionalized with two amino groups have been successfully stabilized and isolated specifically by chemical oxidation using a polyfluoroalkoxyaluminate weak coordinating anion, [Al(ORF)4]− (ORF = OC(CF3)3). These compounds were characterized by UV-Vis-NIR absorption spectroscopy, 1H NMR, EPR, and X-ray single crystal diffraction, respectively. Comprehensive research on their structure–property relationship in conjunction with theoretical calculations has been carried out.

Graphical abstract: Stabilization and isolation of radical cation and dication salts of a tetrathiafulvalene derivative functionalized with amino groups

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Article information

DOI
https://doi.org/10.1039/D0NJ04033A
Article type
Paper
Submitted
11 Aug 2020
Accepted
11 Sep 2020
First published
11 Sep 2020

New J. Chem., 2020,44, 16959-16964

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Stabilization and isolation of radical cation and dication salts of a tetrathiafulvalene derivative functionalized with amino groups

X. Li, Y. Liu, G. Zhu and F. Gao, New J. Chem., 2020, 44, 16959 DOI: 10.1039/D0NJ04033A

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