Issue 31, 2017

Ring strain-dictated divergent fluorinating Prins cyclization or semipinacol rearrangement

Abstract

We have developed ring-strain dictated divergent diastereoselective fluorinating Prins cyclization reactions or semipinacol rearrangement reactions to access tetrahydropyrans containing a fluorohydrin or a carbonyl moiety at quaternary carbon centers under mild conditions, respectively.

Graphical abstract: Ring strain-dictated divergent fluorinating Prins cyclization or semipinacol rearrangement

Supplementary files

Article information

Article type
Communication
Submitted
28 Jun 2017
Accepted
18 Jul 2017
First published
18 Jul 2017

Org. Biomol. Chem., 2017,15, 6478-6482

Ring strain-dictated divergent fluorinating Prins cyclization or semipinacol rearrangement

Y. Liu and Y. Yeung, Org. Biomol. Chem., 2017, 15, 6478 DOI: 10.1039/C7OB01567D

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