Issue 107, 2016, Issue in Progress
From the journal:

RSC Advances

Convenient and efficient synthesis of functionalized unsymmetrical alkynyl sulfides†

J. Doroszuk,a   M. Musiejuk,a   S. Demkowicz,a   J. Rachona  and  D. Witt*a  

* Corresponding authors

a Department of Organic Chemistry, Faculty of Chemistry, Gdansk University of Technology, Narutowicza 11/12, 80-233 Gdansk, Poland
E-mail: chemwitt@pg.gda.pl
Fax: +48 58 3472694

Abstract

We developed a simple and efficient method for the synthesis of functionalized unsymmetrical alkynyl sulfides under mild conditions in good yields. The designed method is based on the reaction of 5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-disulfanyl derivatives with lithium acetylides. The developed method allows the preparation of unsymmetrical alkynyl sulfides bearing additional hydroxyl, carboxyl, or amino functionalities.

Graphical abstract: Convenient and efficient synthesis of functionalized unsymmetrical alkynyl sulfides

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Article information

DOI
https://doi.org/10.1039/C6RA19440K
Article type
Communication
Submitted
01 Aug 2016
Accepted
20 Oct 2016
First published
20 Oct 2016

RSC Adv., 2016,6, 105449-105453

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Convenient and efficient synthesis of functionalized unsymmetrical alkynyl sulfides

J. Doroszuk, M. Musiejuk, S. Demkowicz, J. Rachon and D. Witt, RSC Adv., 2016, 6, 105449 DOI: 10.1039/C6RA19440K

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