Issue 47, 2016

Synthesis and structure of Zr(iv)- and Ce(iv)-based CAU-24 with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

Abstract

Two new MOFs denoted as M-CAU-24 (M = Zr, Ce) based on 1,2,4,5-tetrakis(4-carboxyphenyl)benzene (H4TCPB) were obtained under mild reaction conditions within 15 min. The MOFs with composition [M63-O)43-OH)4(OH)4(H2O)4(TCPB)2] crystallise in the scu topology, a connectivity hitherto unreported for Zr-MOFs with tetracarboxylate linker molecules. Zr-CAU-24 exhibits UV/blue ligand-based luminescence.

Graphical abstract: Synthesis and structure of Zr(iv)- and Ce(iv)-based CAU-24 with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

Supplementary files

Article information

Article type
Communication
Submitted
05 Oct 2016
Accepted
08 Nov 2016
First published
08 Nov 2016
This article is Open Access
Creative Commons BY license

Dalton Trans., 2016,45, 18822-18826

Synthesis and structure of Zr(IV)- and Ce(IV)-based CAU-24 with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

M. Lammert, H. Reinsch, C. A. Murray, M. T. Wharmby, H. Terraschke and N. Stock, Dalton Trans., 2016, 45, 18822 DOI: 10.1039/C6DT03852B

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