Issue 73, 2015

Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6]27− based on abundant metals

Abstract

An eleven iron-containing nanoscale inorganic polyanionic oxide cluster was reported as the first example for exceptional photocatalytic water oxidation. Under optimal conditions, a remarkable turn-over number (TON) of 1815 ± 50 and a turn-over frequency (TOFinitial) of 6.3 s−1 over 1 were achieved for water oxidation.

Graphical abstract: Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6]27− based on abundant metals

Supplementary files

Article information

Article type
Communication
Submitted
03 Jun 2015
Accepted
21 Jul 2015
First published
21 Jul 2015

Chem. Commun., 2015,51, 13925-13928

Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6]27− based on abundant metals

X. Du, Y. Ding, F. Song, B. Ma, J. Zhao and J. Song, Chem. Commun., 2015, 51, 13925 DOI: 10.1039/C5CC04551G

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