Issue 20, 2015

Mirror symmetry breaking upon spontaneous crystallization from a dynamic combinatorial library of macrocyclic imines

Abstract

Spontaneous emergence of solid state chirality and mirror symmetry breaking occurred upon crystallization from a small templated dynamic combinatorial library (DCL) of achiral macrocyclic imines, and depended strongly on the nature of library building blocks (amines, aldehydes, template cations and anions) and crystallization temperature.

Graphical abstract: Mirror symmetry breaking upon spontaneous crystallization from a dynamic combinatorial library of macrocyclic imines

Supplementary files

Article information

Article type
Communication
Submitted
17 Dec 2014
Accepted
29 Jan 2015
First published
03 Feb 2015

Chem. Commun., 2015,51, 4306-4309

Mirror symmetry breaking upon spontaneous crystallization from a dynamic combinatorial library of macrocyclic imines

K. Ziach and J. Jurczak, Chem. Commun., 2015, 51, 4306 DOI: 10.1039/C4CC10083B

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