Synthesis, characterization, and luminescence modulation of a rare barium-tetracarboxylate framework with I2O1 connectivity

Xiao Chen; Sha He; Feiyan Chen; Yunlong Feng

doi:10.1039/C4CE01059K

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Synthesis, characterization, and luminescence modulation of a rare barium-tetracarboxylate framework with I²O¹ connectivity†

Xiao Chen,^a Sha He,^a Feiyan Chen^a and Yunlong Feng*^a

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* Corresponding authors

^a Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, China
E-mail: sky37@zjnu.cn

Abstract

Solvothermal reaction of a tetracarboxylic acid with Ba(NO₃)₂ afforded a barium–organic framework whose single crystal X-ray structure was characterized to have I²O¹ connectivity and 1D channels 15.1 Å in diameter. The luminescence intensity of this MOF can be modulated by ion exchange.

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Article information

DOI: https://doi.org/10.1039/C4CE01059K
Article type: Paper
Submitted: 22 May 2014
Accepted: 18 Jul 2014
First published: 18 Jul 2014

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CrystEngComm, 2014,16, 8706-8709

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Synthesis, characterization, and luminescence modulation of a rare barium-tetracarboxylate framework with I²O¹ connectivity

X. Chen, S. He, F. Chen and Y. Feng, CrystEngComm, 2014, 16, 8706 DOI: 10.1039/C4CE01059K

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