SCHEDULED MAINTENANCE
An efficient synthetic procedure for obtaining manganese carboxylates including a trinuclear cluster [Mn3(PhCO2)6(THF)4]2 and a unique [Mn(PhCO2)2]n chiral 3D network is reported. The procedure involves a simple redox process, in which acidic protons are reduced to gaseous hydrogen by oxidizing metallic manganese under solvothermal conditions.
![Graphical abstract: Efficient synthesis of manganese(ii) carboxylates: from a trinuclear cluster [Mn3(PhCO2)6(THF)4] to a unique [Mn(PhCO2)2]n chiral 3D network](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C3DT53211A&imageInfo.ImageIdentifier.Year=2014)
A. Kornowicz, S. Komorski, Z. Wróbel, I. Justyniak, N. Nedelko, A. Ślawska-Waniewska, R. Balawender and J. Lewiński, Dalton Trans., 2014, 43, 3048 DOI: 10.1039/C3DT53211A
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