Issue 62, 2013
From the journal:

Chemical Communications

Two novel innovanoside dimers from Daphne aurantiaca and a concise total synthesis of diinnovanoside A†

Shuang Liang,‡ab   Shan-Xiang Liu,‡c   Hui-Zi Jin,c   Lei Shan,a   Shi-Chong Yu,d   Yun-Heng Shen,a   Hui-Liang Li,a   Qiu-Ye Wu,d   Qing-Yan Sun*d  and  Wei-Dong Zhang*a  

* Corresponding authors

a Department of Natural Product Chemistry, School of Pharmacy, Second Military Medical University, Shanghai 200433, People's Republic of China
E-mail: wdzhangy@hotmail.com
Fax: +86-21-81871244
Tel: +86-21-81871244

b Shanghai University of Traditional Chinese Medicine, Engineering Research Center of Modern Preparation Technology of TCM, Ministry of Education, Shanghai 201203, People's Republic of China

c School of Pharmacy, Shanghai Jiao Tong University, Shanghai 200240, People's Republic of China

d Department of Organic Chemistry, School of Pharmacy, Second Military Medical University, Shanghai 200433, People's Republic of China
E-mail: sqy_2000@163.com
Fax: +86-21-81871244
Tel: +86-21-81871244

Abstract

Chemical examination of the methanolic extract from the stem bark of Daphne aurantiaca led to the isolation of two innovanoside dimers (1 and 2) with an unusual four-membered cyclobutane ring, together with the isoinnovanoside 3. Their chemical structures and configurations were elucidated by extensive spectral analysis and synthesis.

Graphical abstract: Two novel innovanoside dimers from Daphne aurantiaca and a concise total synthesis of diinnovanoside A

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Article information

DOI
https://doi.org/10.1039/C3CC41811A
Article type
Communication
Submitted
11 Mar 2013
Accepted
26 Apr 2013
First published
01 May 2013

Chem. Commun., 2013,49, 6968-6970

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Two novel innovanoside dimers from Daphne aurantiaca and a concise total synthesis of diinnovanoside A

S. Liang, S. Liu, H. Jin, L. Shan, S. Yu, Y. Shen, H. Li, Q. Wu, Q. Sun and W. Zhang, Chem. Commun., 2013, 49, 6968 DOI: 10.1039/C3CC41811A

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