Issue 4, 1995

Diastereoselective reductions of β-substituted-γ-keto sulfoximines and a novel palladium(0)-catalysed allylic sulfoximine to allylic sulfinamide rearrangement

Abstract

The reduction of β-substituted-γ-keto N-tosyl Sulfoximines is highly diastereoselective and the allylic sulfoximines products undergo a facile rearrangement to allylic sulfinamides in the presence of a palladium(0) catalyst.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 445-446

Diastereoselective reductions of β-substituted-γ-keto sulfoximines and a novel palladium(0)-catalysed allylic sulfoximine to allylic sulfinamide rearrangement

S. G. Pyne, Z. Dong, B. W. Skelton and A. H. White, J. Chem. Soc., Chem. Commun., 1995, 445 DOI: 10.1039/C39950000445

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