Issue 17, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

The preparation and characterization of the mixed valence complex dianion [Mn3(CO)6(µ2-NO2)4(µ2-ONO)2]2–

Brian F. G. Johnson,   Anke Sieker,   Alexander J. Blake  and  Richard E. P. Winpenny  

Abstract

Treatment of Mn(Co)5Cl With trimethylamine N-Oxide In CH2Cl2 in the presence of [PPN]NO2[PPN+=(Ph3P)2N+] yields the new dianion [Mn3(CO)6(µ2-NO2)4(µ2-ONO)2]2–, which has been shown to contain a trinuclear Mn3 mixed valence unit linked by both nitro- and nitrito-bridges.

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Article information

DOI
https://doi.org/10.1039/C39930001345
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1345-1346

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The preparation and characterization of the mixed valence complex dianion [Mn3(CO)6(µ2-NO2)4(µ2-ONO)2]2–

B. F. G. Johnson, A. Sieker, A. J. Blake and R. E. P. Winpenny, J. Chem. Soc., Chem. Commun., 1993, 1345 DOI: 10.1039/C39930001345

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