Issue 19, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

Formation of a homoleptic unbridged metal–metal bonded isocyanide dimer of ruthenium(I) by metal–carbon bond cleavage in [Ru(1–2,5-η-C8H13)(CN-xylyl)4]PF6: the X-ray structure determination of [Ru2(CN-xylyl)10][BPh4]2

Anthony A. Chalmers,   David C. Liles,   Elsie Meintjies,   Hester E. Oosthuizen,   Jan A. Pretorius  and  Eric Singleton  

Abstract

Refluxing [Ru(1–2,5-η-C8H13)(CN-xylyl)4]PF6 in [2H6]acetone gives C8H13D and [Ru2(CN-xylyl)10][PF6]2; an X-ray structure determination of [Ru2(CN-xylyl)10][BPh4]2 shows the cation to be an unbridged, metal–metal bonded dimer of ruthenium(I) containing eclipsed 2,6-dimethylphenyl isocyanide ligands.

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Article information

DOI
https://doi.org/10.1039/C39850001340
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1340-1341

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Formation of a homoleptic unbridged metal–metal bonded isocyanide dimer of ruthenium(I) by metal–carbon bond cleavage in [Ru(1–2,5-η-C8H13)(CN-xylyl)4]PF6: the X-ray structure determination of [Ru2(CN-xylyl)10][BPh4]2

A. A. Chalmers, D. C. Liles, E. Meintjies, H. E. Oosthuizen, J. A. Pretorius and E. Singleton, J. Chem. Soc., Chem. Commun., 1985, 1340 DOI: 10.1039/C39850001340

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