The replacement of the trans-CO group by Br– in cationic [(CO)5W![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CNCR2]AlBr4 complexes causes a drastic change in the geometry of the CNCR2 ligand; the molecular structure of the phenyl-substituted product, trans-Br(CO)4W[CNCPh2], is established by single crystal X-ray diffraction.
H. Fischer, F. Seitz and J. Riede, J. Chem. Soc., Chem. Commun., 1985, 537 DOI: 10.1039/C39850000537
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