Issue 42, 2008
From the journal:

Dalton Transactions

First regioselective cyclometalation reactions of cobalt in arylketones: C–H versus C–F activation†

Sebnem Camadanli,*ab   Robert Beck,a   Ulrich Flörkec  and  Hans-Friedrich Kleina  

* Corresponding authors

a Eduard-Zintl Institut, Technische Universität Darmstadt, Petersenstrasse 18, Darmstadt, Germany

b Leibniz Institute for Surface Modification, Permoserstrasse 15, Leipzig, Germany
E-mail: sebnem.camadanli@iom-leipzig.de
Fax: +49 341 235 2313
Tel: +49 341 235 2377

c Anorganische und Analytische Chemie, Universität Paderborn, Warburger Strasse 100, Paderborn, Germany

Abstract

Phenyl ketones react smoothly under mild conditions with low valent cobalt(I) adducts to form new and stable five-membered cobaltacycles via C–H and C–F activation.

Graphical abstract: First regioselective cyclometalation reactions of cobalt in arylketones: C–H versus C–F activation

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Article information

DOI
https://doi.org/10.1039/B813419G
Article type
Communication
Submitted
01 Aug 2008
Accepted
12 Aug 2008
First published
05 Sep 2008

Dalton Trans., 2008, 5701-5704

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First regioselective cyclometalation reactions of cobalt in arylketones: C–H versus C–F activation

S. Camadanli, R. Beck, U. Flörke and H. Klein, Dalton Trans., 2008, 5701 DOI: 10.1039/B813419G

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