Issue 3, 2006
From the journal:

Chemical Communications

Relevance of electron transfer mechanism in electrocatalysis: the reduction of organic halides at silver electrodes

Abdirisak A. Isse,a   Luigi Falciola,b   Patrizia R. Mussinib  and  Armando Gennaro*a  

* Corresponding authors

a Department of Chemical Sciences, University of Padova, via Marzolo 1, 35131 Padova, Italy
E-mail: armando.gennaro@unipd.it
Fax: +39-049-8275239
Tel: +39-049-8275132

b Department of Physical Chemistry and Electrochemistry, University of Milano, Via Golgi 19, 20133 Milano, Italy
E-mail: patrizia.mussini@unimi.it
Fax: +39-02-50314300
Tel: +39-02-50314211

Abstract

The mechanism of dissociative electron transfer (ET) to a series of organic chlorides has been investigated both at an inert electrode and at a catalytic surface such as Ag; electrocatalysis is important only when breaking of the carbon–halogen bond is concerted with the ET.

Graphical abstract: Relevance of electron transfer mechanism in electrocatalysis: the reduction of organic halides at silver electrodes

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Article information

DOI
https://doi.org/10.1039/B513801A
Article type
Communication
Submitted
29 Sep 2005
Accepted
08 Nov 2005
First published
02 Dec 2005

Chem. Commun., 2006, 344-346

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Relevance of electron transfer mechanism in electrocatalysis: the reduction of organic halides at silver electrodes

A. A. Isse, L. Falciola, P. R. Mussini and A. Gennaro, Chem. Commun., 2006, 344 DOI: 10.1039/B513801A

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