Issue 5, 2004
From the journal:

Journal of Materials Chemistry

Open-framework zinc and cobalt phosphates synthesized by the tributylphosphate route†

S. Neeraj,a   C. N. R. Raoab  and  Anthony K. Cheetham*a  

* Corresponding authors

a Materials Research Laboratory, University of California Santa Barbara, U.S.A
E-mail: cheetham@mrl.ucsb.edu
Fax: 1-805-8938797

b Jawaharlal Nehru Center for Advanced Scientific Research, Jakkur P.O., Bangalore, India

Abstract

By employing tributylphosphate as the source of phosphorus, several open-framework zinc and cobalt phosphates have been prepared hydrothermally. Of the three new zinc phosphates [C6N2H18][Zn(HPO4)2], I, has a linear chain structure while [C4N2H14][Zn5(PO4)4(H2O)], II, [NH4][H3O][Zn4(PO4)3]2·H2O, III, have three-dimensional structures. Of the three new cobalt phosphates described, [C5N2H14][Co(HPO4)2], IV, and [C5N2H14][Co(HPO4)2], V, have linear chain structures, while [C4N2H12]3 [Co2(OH)(HPO4)3]2, VI, has a complex double chain structure. The study shows that the use of the organophosphate yields a variety of architectures of metal phosphates.

Graphical abstract: Open-framework zinc and cobalt phosphates synthesized by the tributylphosphate route

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Article information

DOI
https://doi.org/10.1039/B311529A
Article type
Paper
Submitted
17 Nov 2003
Accepted
25 Nov 2003
First published
20 Jan 2004

J. Mater. Chem., 2004,14, 814-820

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Open-framework zinc and cobalt phosphates synthesized by the tributylphosphate route

S. Neeraj, C. N. R. Rao and A. K. Cheetham, J. Mater. Chem., 2004, 14, 814 DOI: 10.1039/B311529A

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