Issue 2, 1973
From the journal:

Journal of the Chemical Society, Dalton Transactions

Transition-metal carbonyl derivatives of the germanes. Part IV. Germylpentacarbonylrhenium

K. M. Mackay  and  S. R. Stobart  

Abstract

Physical and spectroscopic properties of germylpentacarbonylrhenium, GeH3Re(CO)5, (I) prepared through reaction of germyl bromide with NaRe(CO)5, are reported and compared with those of the manganese analogue and other related complexes. A further product, isolated in very low yield during the formation of (I), is tentatively identified as bis(pentacarbonylrhenium)germane. GeH2[Re(CO)5]2(II). Ions arising from transfer of hydrogen from Ge to Re are of unusually high abundance in the mass spectrum of (I).

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Article information

DOI
https://doi.org/10.1039/DT9730000214
Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 214-217

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Transition-metal carbonyl derivatives of the germanes. Part IV. Germylpentacarbonylrhenium

K. M. Mackay and S. R. Stobart, J. Chem. Soc., Dalton Trans., 1973, 214 DOI: 10.1039/DT9730000214

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