The individual diastereoisomers that constitute the unusual methylenecyclopropane containing α-amino acid hypoglycin A have been synthesised utilising the Sharpless epoxidation to permit an asymmetric methylene cyclopropane synthesis.
J. E. Baldwin, R. M. Adlington, D. Bebbington and A. T. Russell, J. Chem. Soc., Chem. Commun., 1992, 1249 DOI: 10.1039/C39920001249
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