Issue 18, 1986

Pentaco-ordinate silicon compounds in synthesis: chemo- and stereo-selective reduction of carbonyl compounds using trialkoxy-substituted silanes and alkali metal alkoxides

Abstract

Carbonyl compounds are reduced with trialkoxy-substituted silane to the corresponding alcohols chemo- and stereo-selectively in the presence of alkali metal alkoxide under mild conditions; reduction occurs very smoothly by using an alkoxide derived from pinacol as a bidentate ligand.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1411-1412

Pentaco-ordinate silicon compounds in synthesis: chemo- and stereo-selective reduction of carbonyl compounds using trialkoxy-substituted silanes and alkali metal alkoxides

A. Hosomi, H. Hayashida, S. Kohra and Y. Tominaga, J. Chem. Soc., Chem. Commun., 1986, 1411 DOI: 10.1039/C39860001411

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