Issue 11, 2010
From the journal:

CrystEngComm

Silver nanofibers from the nanorods of one-dimensional organometallic coordination polymers†

Kamran Akhbaria  and  Ali Morsali*a  

* Corresponding authors

a Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14115-175, Tehran, Islamic Republic of Iran

Abstract

A 1D pencil shaped organometallic coordination polymer, [Ag2(μ5-TPOAc)2]n (1) [TPOAc− = triphenylacetate], has been synthesized and characterized and its structure was determined by X-ray crystallography. There are two types of Ag+ ions, which form strong η2 Ag2–C π bonds, two weak η1 Ag1⋯C π interactions and strong Ag–Ag interactions, resulting in the formation of C2⋯Ag1O3Ag2 and Ag2O3C2Ag2 moieties with very interesting structures. In addition we prepared metal coordination nano-polymers (MCNPs) of compound 1 by ultrasonic process where pyrolysis of compound 1 nanorods, as a template, result in silver nanofibers.

Graphical abstract: Silver nanofibers from the nanorods of one-dimensional organometallic coordination polymers

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Article information

DOI
https://doi.org/10.1039/C002740E
Article type
Communication
Submitted
10 Feb 2010
Accepted
11 May 2010
First published
10 Jun 2010

CrystEngComm, 2010,12, 3394-3396

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Silver nanofibers from the nanorods of one-dimensional organometallic coordination polymers

K. Akhbari and A. Morsali, CrystEngComm, 2010, 12, 3394 DOI: 10.1039/C002740E

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