Issue 3, 2002
From the journal:

Chemical Communications

The biosynthesis of bisvertinolone: evidence for oxosorbicillinol as a direct precursor

Naoki Abe,*a   Tadaharu Arakawaa  and  Akira Hirotaa  

* Corresponding authors

a School of Food and Nutritional Sciences, University of Shizuoka, 52-1 Yada, Shizuoka, Japan
E-mail: abe@fns1.u-shizuoka-ken.ac.jp
Fax: +81-54-264-5099
Tel: +81-54-264-5555

Abstract

Biosynthetic incorporation of labeled sodium acetate into oxosorbicillinol in Trichoderma sp. USF-2690 suggests that oxosorbicillinol is derived from six acetate units, and subsequent bioconversion of the labeled oxosorbicillinol to bisvertinolone in the fermentation of the strain suggests that bisvertinolone is biosynthesized from oxosorbicillinol and sorbicillinol in a Michael-type reaction.

Graphical abstract: The biosynthesis of bisvertinolone: evidence for oxosorbicillinol as a direct precursor

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Article information

DOI
https://doi.org/10.1039/B109505F
Article type
Communication
Submitted
18 Oct 2001
Accepted
05 Dec 2001
First published
07 Jan 2002

Chem. Commun., 2002, 204-205

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The biosynthesis of bisvertinolone: evidence for oxosorbicillinol as a direct precursor

N. Abe, T. Arakawa and A. Hirota, Chem. Commun., 2002, 204 DOI: 10.1039/B109505F

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