Issue 13, 2015

Solvent-free synthesis of new inorganic–organic hybrid solids with finely tuned manganese oxalate structures

Abstract

Three manganese phosphate-oxalates have been synthesized under solvent-free conditions. These inorganic–organic hybrid solids are based on a pcu-type topology with nanobelt-like, sql-, and cds-type manganese oxalate skeletons, respectively. The amine molecules play a novel structure-directing role for the formation of different metal–organic skeletons within a specific framework topology.

Graphical abstract: Solvent-free synthesis of new inorganic–organic hybrid solids with finely tuned manganese oxalate structures

Supplementary files

Article information

Article type
Communication
Submitted
30 Jan 2015
Accepted
19 Feb 2015
First published
26 Feb 2015

Dalton Trans., 2015,44, 5974-5977

Author version available

Solvent-free synthesis of new inorganic–organic hybrid solids with finely tuned manganese oxalate structures

L. Luan, J. Li, C. Yin, Z. Lin and H. Huang, Dalton Trans., 2015, 44, 5974 DOI: 10.1039/C5DT00431D

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