Issue 12, 2000
From the journal:

Chemical Communications

The kinetic resolution of allylic alcohols by a non-enzymatic acylation catalyst; application to natural product synthesisElectronic supplementary information (ESI) available: full experimental details. See http://www.rsc.org/suppdata/cc/b0/b002041i/

Stéphane Bellemin-Laponnaz,a   Jennifer Tweddell,a   J. Craig Ruble,a   Frank M. Breitlinga  and  Gregory C. Fu*a  

* Corresponding authors

a Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA.
E-mail: gcf@mit.edu

Abstract

A planar-chiral DMAP derivative is shown to serve as an effective catalyst for the kinetic resolution of allylic alcohols; to illustrate its practical utility, the catalyst is applied to the resolution of two alcohols that have been employed as intermediates in recent natural product total syntheses.

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Article information

DOI
https://doi.org/10.1039/B002041I
Article type
Communication
Submitted
07 Mar 2000
Accepted
24 Apr 2000
First published
22 May 2000

Chem. Commun., 2000, 1009-1010

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The kinetic resolution of allylic alcohols by a non-enzymatic acylation catalyst; application to natural product synthesis

S. Bellemin-Laponnaz, J. Tweddell, J. C. Ruble, F. M. Breitling and G. C. Fu, Chem. Commun., 2000, 1009 DOI: 10.1039/B002041I

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