Abstract
Radio frequency (RF) magnetron sputtering was used to deposit tungsten disulfide (WS2) thin films on top of soda lime glass substrates. The deposition power of RF magnetron sputtering varied at 50, 100, 150, 200, and 250 W to investigate the impact on film characteristics and determine the optimized conditions for suitable application in thin-film solar cells. Morphological, structural, and opto-electronic properties of as-grown films were investigated and analyzed for different deposition powers. All the WS2 films exhibited granular morphology and consisted of a rhombohedral phase with a strong preferential orientation toward the (101) crystal plane. Polycrystalline ultra-thin WS2 films with bandgap of 2.2 eV, carrier concentration of 1.01 × 1019 cm−3, and resistivity of 0.135 Ω-cm were successfully achieved at RF deposition power of 200 W. The optimized WS2 thin film was successfully incorporated as a window layer for the first time in CdTe/WS2 solar cell. Initial investigations revealed that the newly incorporated WS2 window layer in CdTe solar cell demonstrated photovoltaic conversion efficiency of 1.2% with Voc of 379 mV, Jsc of 11.5 mA/cm2, and FF of 27.1%. This study paves the way for WS2 thin film as a potential window layer to be used in thin-film solar cells.
Similar content being viewed by others
Introduction
For many decades, transition metal dichalcogenides (TMDCs) are among the promising materials in a wide range of applications, but their superior performance in complex applications has attracted extensive research attention. TMDCs, particularly MoS2 and WS2, have recently raised particular concerns for the photovoltaic community1,2 due to their suitable bandgaps in the range of 1–2 eV and high absorption coefficient of over 105 cm−1 3,4,5,6,7. Although WS2 is more abundant in the Earth’s crust, cheaper, and less toxic compared to other TMDC materials, the development of WS2 in thin-film solar cells remains in its infancy compared with similar photovoltaic materials. Very recently, tungsten disulfide (WS2) has become the focus of thin-film solar cell materials due to its opto-electrical properties. Although the individual crystals of this material have been studied in optical devices, only a few studies have been carried out concerning the photovoltaic properties of a thin film. An important characteristic that is seldom addressed is its tunable bandgap. WS2 can exhibit a high direct bandgap (>2 eV) and a low indirect bandgap (<1.5 eV) depending on its fabrication technique8. It has a considerably large size of W atoms that can tailor its structural properties based on its application8,9.
A typical thin-film solar cell structure comprises a highly doped coating on a substrate where a similar but moderately doped absorber layer is deposited on top of it. Above the absorber layer, a heavily but opposite conductive material is doped that functions as an emitter or window layer7. The window layer in a heterojunction thin-film solar cell is primarily used to form a p-n junction with the absorber layer. This layer is desired to achieve a high bandgap, small thickness, and low series resistance for high optical throughput. Absorber layers must have high optical absorption coefficient with high mobility, good carrier lifetime, and enhanced crystallographic properties10,11. CdS is widely used as a window or buffer layer material in photovoltaic devices due to its suitable bandgap and enhancement properties in the interface chemistry between light absorber and window layer during fabrication. However, the toxicity of Cd12 and hazardous impact of CdCl2 treatment during fabrication13 of CdTe-based solar cells are the major disadvantages of CdS. Thus, researchers have sought to investigate other materials for window layer application. Several environmentally friendly, wide bandgap materials such as ZnS, ZnSe, and ZnO are currently being investigated to replace CdS10,14,15. Researchers have yet to find an ideal window layer material to replace toxic CdS.
TMDC thin films for photovoltaic application are grown by a variety of methods. At least two groups deposited WS2 and MoS2 by chemical vapor deposition (CVD). In both the cases, MoS2 films exhibited good photoconductivity, while WS2 did not. WS2 films have also been deposited from tungsten by sulfurization16,17 or sulfurizing tungsten oxide films17,18 or from tungsten targets by reactive magnetron sputtering in Ar/H2S atmosphere19,20,21 or by electrodeposition22; however, incorporating WS2 for photovoltaic applications has yet to be achieved. As-deposited films were found sulfur-deficient and exhibited poor crystallographic quality, a porous morphology, and a high defect density23,24. Seegar et al. opined that low sputtering pressures with increased particle bombardment (deposition power) of the growing film causes significant changes in morphology but increases defect density and incorporates impurities to films; these impurities need to be addressed when the films are used for solar cells25,26. As radiofrequency (RF) magnetron sputtering is a plasma- or ion-assisted deposition process, the slightest variation in deposition parameters may cause changes in structure and bonding of the deposited material27,28. Such changes may lead to both advantageous and detrimental effects for photovoltaic application. For this reason, deposition parameters play a wide role in the preferential growth process in sputtering. Thus, optimization of growth parameters in RF magnetron sputtering is crucial. To investigate the suitable application of WS2 in solar cells, we extensively studied the morphological, structural, and optoelectrical properties of WS2 deposited by RF magnetron sputtering under different deposition powers. Finally, a CdTe-WS2 complete thin-film solar cell was successfully fabricated using WS2 as a window layer for the first time. The study also aimed to eliminate pinholes in sputtered films to improve the stability and efficiency of the solar cell device.
Methodology
WS2 thin-film deposition
WS2 thin film was deposited by RF magnetron sputtering deposition, which is one of the prominent physical vapor deposition techniques under high vacuum condition. In this study, deposition was carried out on soda lime glass substrates of 7.5 cm × 2.5 cm × 0.2 cm. They were pre-cleaned by sequential cleaning, such as mechanical scrubbing, followed by acetone–methanol–deionized water in an ultrasonic bath and later dried with N2 gas flow. A 50 mm diameter WS2 (99.99%) sputtering target (supplied by Kurt. J. Lesker) was used as the source material. Initially sputtering chamber was purged twice to remove unwanted components from the chamber. The chamber’s base pressure was brought down to 10−6 torr by a turbomolecular pump. During deposition, the working pressure was maintained at 10−2 torr to instigate the plasma. The target-to-substrate distance (sputter down) and substrate holder rotation were fixed at 8 cm and 10 rpm, respectively. Deposition parameters used for this study are shown in Table 1. During the deposition process, the substrate temperature was fixed at 100 °C. All the samples were stored inside the sputtering chamber upon completion of deposition until the substrate temperature fell to room temperature to prevent as-grown films from being oxidized.
Full device fabrication
The optimized WS2 thin film was incorporated as a window layer in lieu of CdS in CdTe solar cell. For the initial study, the basic superstrate structure of the CdTe solar cell was chosen. Full device fabrication included the stack of five layers, namely, indium tin oxide (ITO) for the transparent conducting oxide, the n-type WS2 window layer, the p-type absorber CdTe, Cu-doped graphite paste for improved ohmic contact, and silver (Ag) as back contact. The complete cell was fabricated by sputtering as reported by previous researchers29. Figure 1 represents the structure and full cell device fabrication process.
Film characterization
The structural and crystalline properties of the as-grown films were examined by a BRUKER aXS-D8 Advance CuKα diffractometer at room temperature. X-ray diffraction (XRD) patterns were recorded in the 2ϴ range of 10°–80° with a step size of 0.05° using Cu Kα radiation wavelength λ = 0.15408 nm. Atomic force microscopy (AFM) was used to examine the surface pattern and roughness of the film. Grain size, surface morphology, and cross-sectional views were observed by using a Carl Zeiss Merlin field-emission scanning electron microscope (FESEM) operated at 3 kV. Electronic properties such as carrier concentration, mobility, and resistivity were measured by a Hall Effect measurement system (HMS ECOPIA 3000) with a magnetic field of 0.57 T and probe current of 100 nA for all the samples. Characterization on optical properties was carried out to determine the absorbance, transmittance, and optical bandgap. These measurements were performed at room temperature by using a Perkin Elmer Lambda 950 UV-Vis-NIR spectrophotometer. The absorption coefficient and bandgaps were calculated from Tauc plots. Pinholes were investigated by keeping as-deposited samples over a light source, and the adhesiveness of films was tested by the “Scotch tape” method. To evaluate the performance of full cells, newly fabricated cells underwent light I-V testing. The light source in the I–V tester replicated the standard 1.5 AM G spectrum. Dark I–V data were also obtained using the same equipment.
Results and Discussion
Adhesiveness of film
Adhesiveness is a pre-requirement for any deposition on substrate. The Scotch tape method is an effective technique to check the adhesiveness of any film30. The Scotch tape test is usually conducted on samples immediately after the deposition process. Thus, it was performed after the natural cooling of substrates. Table 2 shows the outcome of the Scotch tape test with respect to different powers. Most of the films showed good adherence to the SLG substrates, except for the few films that were deposited at high deposition power. Some elemental WS2 was observed at deposition of 250 W. In principle, sputtering is the bombardment of particles/species with high energy. A threshold energy for the discharge of atomic species from the target material exists, below which the atom will not be “sputtered.” The yield will increase with the application of deposited power. However, if high input of power is superimposed with its default energy, it causes the bombarded particles’ with a very high rate and causes to bounce the particles from substrate. Therefore, at very high energies due to high deposition power, the yield of films decreases and reduces the adhesion of the film31.
Pinhole elimination
Pinholes were observed by illuminating the metallic film on glass from behind, which sometimes referred to as pin windows. The metallic film will attenuate light when viewed from the front, except for a scattering of bright light pinpricks. The pinpricks of light are often almost circular in shape where there is an area of unmetallized film. These unmetallized areas are primarily caused by the metallization of dust or debris on the surface as the film passes through the deposition zone. However, sometimes after the debris is moved, an un-metallized area that corresponds to the debris’ shadow shape remains. Occasionally, the debris does not roll away but slides away, so the pinhole may also have a scratch track leading away from the unmetallized area. There are two types of pinholes; natural and artificial. Natural pinholes rarely occur and are difficult to eliminate as they come with the source material32. However, artificial pinholes can be eliminated easily by using different techniques. Figure 2 exhibits the pinhole reduction technique inside the sputtering chamber. In this particular experiment, pinholes were effectively removed by changing the substrate-to-target distance from 8 cm to 10.6 cm.
Film morphology
Figure 3 shows the thickness–power relationship of as-grown WS2 for different RF powers. The film thickness increased with the increase in deposition power. However, this phenomenon was only applicable up to 200 W in this study. Above this power, the film thickness was reduced because of the high energetic bombardment of sputtered atoms, which caused the atoms to bounce back from substrates.
FESEM images of WS2 thin films presented in Fig. 4 reveal the surface morphologies of sputtered WS2 thin films at different deposition powers. In this case, the thickness of the film was retained at 350 nm. Our literature review indicated that films sputtered at low deposition power exhibit porous microstructures while films sputtered at high deposition power exhibit dense microstructures33. The number of particles received at the substrate increases with the increase in deposition power, thereby resulting in a dense microstructure. At low deposition power, the deposition rate decreases and the number of species arriving at the surface of the substrate is reduced, resulting in a porous microstructure. In this study, all the films showed a smooth morphology and revealed a dense microstructure for deposition powers of 100 W and above. However, no porous microstructure was observed in the case of WS2. Moreover, the as-grown WS2 thin films with different RF powers showed granular morphology. EDX analysis revealed that all the films exhibited a sulfur deficit (Fig. 5). The highest sulfur-to-tungsten ratio (1: 1.55) was found at 200 W deposition power. Grain size was calculated with ImageJ software29, and the results revealed that grain size increased with the deposition power. The highest grain size of 76.25 nm was found at 150 W deposition power, whereas the lowest of 4.86 nm was found at 50 W deposition power. The average grain size at a deposition power of 150 W and above was 26.74 nm. Thus, a deposition power of 150 W and above has insignificant effects on the grain size of WS2 thin film.
The roughness of the deposited film was measured by atomic force microscopy (AFM). Figure 6 shows the average roughness of the deposited films. The film roughness decreased with the increase in power, but hardly any changes in roughness were observed after a certain level of input power. The ratio between roughness and thickness decreased with power due to the non-formation of droplets and increment of thickness. This ratio remained almost the same between 150 and 250 W. Figure 7 illustrates the relationship between roughness/thickness and power. The probability of absorbance increased when light waves were scattered. Low roughness on the film surface facilitates light waves to transfer easily without scattering. Thus, a high deposition power is necessary when considering WS2 as a window layer material.
Structural properties
Figure 8 shows the XRD patterns for as-sputtered WS2 films at different deposition powers where the 2ϴ angle ranges from 10° to 80°. All films exhibited two primary peaks of (101) and (112) orientations, indicating the polycrystalline nature of the as-sputtered WS2 films. The obtained XRD patterns of this study matched well with the standard XRD pattern documented in JCPDS-00-035-0651 file. All the films that are in 3R phase are semiconducting in nature34. The most intense peak was at 2ϴ = 33.8°, which corresponded to the preferred orientation of the (101) plane. The highest peak was found for two deposition powers, such as 50 and 150 W. However, the β value was almost the same for all variations. The β value represents the deterioration of crystalline properties of the film, and it is inversely proportional to the crystallite size (L)35.
The average particle size or crystallite size was calculated from the broadening of the (101) peak using the Scherrer equation36
where L, λ, β, and θ are the crystallite size, wavelength, FWHM, and angle between the incident and scattering planes, respectively.
Crystalline size was calculated and found to range from 93.97 Å to 62.43 Å. Grains with different relative orientations and positions create differences in phase variations when light waves are scattered by them. The large number of grains with different orientations result in the displacement of atom while forming crystal lattice. The lattice strains exhibited displacement of atoms from their original lattice positions, possibly due to the high energetic deposition. A low strain signifies high crystallinity37,38. Strain was calculated by the following relation:
where \(\varepsilon \) is the strain. Figure 9 shows the variations in crystallinity and strain with respect to different deposition powers. At low deposition power, films exhibited high crystallite size, and the best results were observed at 150 W. As the power exceeded 150 W, the film crystallinity decreased, whereas strain increases. A deposition power of 200 W yielded the highest strain in the crystal structure. This phenomenon could be described as the impact of collisions between sputtered atoms. During sputtering, atoms with high energy bombard to the substrate. When the applied power is extremely high, atoms collide heavily during the formation of film on the substrate. This heavy collision between atoms deforms the crystallite structure at the edge, which increases strain to the film.
Strain and dislocation density of the film followed the same trend as reported by previous researchers. A high strain leads to the increased number of dislocation density in crystalline structure35,38. Thus, at 200 W deposition power, the dislocation density of as-grown WS2 thin film was the highest than that of the others. A high dislocation signifies that dislocations are separated by a distance greater than the interatomic distances. This unique property leads to a high optical bandgap of as-grown thin films39.
Optical properties
The optical behavior of the as-deposited WS2 thin films at different RF powers was characterized by UV-VIS spectrometry. The absorbance of as-deposited films was calculated by the Beer–Lambert law, and the optical properties of the WS2 film are shown in Fig. 8. The Beer–Lambert law (or Beer’s law) is the linear relationship between the absorbance and concentration of an absorbing species. The general Beer–Lambert law is usually written as follows40:
where A is the measured absorbance, a(λ) is a wavelength-dependent absorption coefficient, b is the path length, and c is the analyte concentration. Transmittance is considered the inverse of absorbance41. The highest transmittance of as-grown WS2 film was observed for 200 W deposition power, which was over 60% at 550 nm. This result demonstrated the potential use of WS2 as a window layer material. Figure 10 depicts the transmittance of WS2 under different RF deposition powers.
A Tauc Plot is commonly used to determine the optical bandgap of semiconducting materials in the research community. A Tauc plot generally shows the quantity of the abscissa (the energy of the light spectrum) and the quantity (αhν)1/n on the ordinate, where α is the absorption coefficient of the material42,43. The equation used to determine the bandgap is expressed as follows:
Here, α is the measured absorption coefficient (cm−1) near the absorption edge, A is a constant, hν is the photon energy (eV), Eg is the optical bandgap (eV), and n is a constant. The value of n is determined from the nature of optical transition. n = 2 or 3 was adopted for indirect allowed and indirect forbidden transition, respectively. n = 1/2 or 3/2 was adopted for direct allowed and direct forbidden transition, respectively.
The optical bandgap of WS2 for various RF powers was evaluated by using the Tauc plot shown in Fig. 11. The optical bandgap of as-deposited WS2 thin films ranged from 1.7 eV to 2.2 eV. The results were well matched with the findings of a previous study44. These obtained results were highly desirable for photovoltaic materials and give strong recommendations to use WS2 as a photovoltaic material.
Electrical properties
Hall effect measurement, invented by E.T Hall in 1879, is important for photovoltaic materials because it shows a semiconductor’s resistivity, mobility, and carrier density. Mobility is a measure of the epitaxial layer’s impurity content, quality, and homogeneity. Resistivity is the ratio of the electrical field to the current density45. Electrical properties of as-deposited WS2 films were subjected to Hall effect measurement. All the results, such as carrier concentration, hall mobility, resistivity, and conductivity. are summarized in Table 3.
The carrier concentration and mobility of as-deposited films increased but resistivity decreased with the increase in RF power. The highest carrier concentration was observed at 250 W RF power with resistivity as low as 0.116 Ω-cm. At 200 W RF power, film resistivity was 0.135 Ω-cm with moderate mobility and high carrier concentration. During sputtering, a threshold energy for the release of an atom from the target was noted, below which the atom was not “sputtered.” When this threshold energy increased, it increased the deposition rate and carrier concentration. Therefore, conductivity is proportional to the product of mobility and carrier concentration. For instance, the same conductivity can be observed from a low carrier concentration but high mobility and vice versa44,46. When the deposition power increased, the carrier concentration increased without changing the conductivity of the film. Moreover, all the films exhibited n-type conductivity at all the applied deposition powers.
Comparative study of WS2
Photovoltaic materials should be inexpensive and abundant. They should have good carrier concentration properties for both minority and majority carriers, low carrier recombination loss in grain boundaries, and adhesive to the surface47. Table 4 depicts the findings of a comparative study on the properties of existing photovoltaic materials (CdTe and CdS)48 and examined WS2. The photovoltaic optoelectrical properties of CdS and PVD-grown WS2 were similar. Moreover, from the perspective of material properties, WS2 is a non-toxic, abundant, adhesive, and semiconducting material. Thus, this study proposes to incorporate WS2 as a window layer in thin-film solar cells.
Full device outcome
To determine the reliability and evaluate performance, we incorporated WS2 thin film with 200 W deposition power as the window layer in CdTe/WS2 solar cell. Full ITO/WS2/CdTe/C/Ag devices were fabricated and examined. Figure 12(a) shows the SEM image of the as-deposited cell (three layers). EDX line scan (Fig. 12(b)) confirmed the atomic percentage of all elements present in the fabricated device. To evaluate the performance of the WS2-incorporated solar cell, it was characterized by an IV tester; it had an efficiency of 1.20%. Figure 13 shows the dark and light IV curves of the fabricated solar cell.
The device demonstrated an efficiency of 1.20% with Jsc = 10.45 mA/cm2, Voc = 0.39 V, and FF = 29.42%. The dark IV curve showed that the leakage current was high in the fabricated cell, which indicated imperfections in the p-n junction. In the light IV curve, the fabricated cell presented increased series and parallel resistances under illumination, which resulted in lowered efficiency. All these drawbacks need to be addressed to achieve elevated efficiency.
Conclusion
The first part of this study investigated the effect of RF deposition power on the sputter-grown WS2 film’s properties. Efforts were made to find the optimum film characteristics suitable for photovoltaic applications. In practice, pinhole reduction was achieved by optimizing the source-to-substrate distance. The adhesive test was also conducted to determine the best suited ones. For the range of growth conditions investigated here, deposited films were found to exhibit diffraction peaks corresponding to the (101) and (112) planes. All the films exhibited 3-R phase with granular morphology. By analyzing all the characteristics of as-deposited WS2 thin films grown at different RF powers, 200 W of RF deposition power was found suitable for using WS2 as a window layer material as it provided smooth surface morphology with an optical bandgap of 2.2 eV and high transmittance percentage to the visible light spectrum. At this deposition power, electrical properties such as carrier concentration and resistivity were 1.01 × 1019 cm−3 and 0.135 Ω-cm. respectively. These values agreed with the properties of the window layer material in solar cell devices.
The second part of the study was the successful demonstration of the incorporation of WS2 as photovoltaic material. With this optimized deposition parameter, WS2 thin film was successfully fabricated for the very first time as a window layer in CdTe solar cells. The new device (ITO/WS2/CdTe/Cu:C/Ag) exhibited Voc = 0.39 V, Jsc = 10.45 mA/cm2, fill factor = 29.42%, and efficiency = 1.2%. The lowered efficiency was due to the optimized layer thickness of all layers and suitable ohmic contact, but these parameters were not investigated in this study. Nevertheless, this work successfully incorporated the low-cost non-toxic material WS2 in a solar cell device for the first time. Future work should focus on optimizing the device parameters, tuning the WS2 bandgap, analyzing defects in the interfaces, lowering cell resistance, and increasing the efficiency of solar cells.
References
Zhao, W. et al. Lattice Dynamics in Mono- & Few-Layer Sheets of WS2 & WSe2. Nanoscale 5, 9677–9683 (2013).
Wang, Q. H., Kalantar-Zadeh, K., Kis, A. & Coleman, J. N. Strano. Electronics and optoelectronics of two-dimensional transition metal di-chalcogenides. Nature Nanotechnol 7, 699–712 (2012).
Ganatra, R. & Zhang, Q. Few-Layer MoS2: A Promising Layered Semiconductor. ACS Nano 8(5), 4074–4099 (2014).
Chen, S., Zheng, C., Fuhrer, M. S. & Yan, J. Helicity-Resolved Raman Scattering of MoS2, MoSe2, WS2, & WSe2 Atomic Layers. Nano Lett. 15, 2526–2532 (2015).
Dickinson, R. G. & Pauling, L. The crystal structure of molybdenite. J. Am. Chem. Soc. 45, 1466 (1923).
Lewerenz, H. J., Heller, A. & Di Salvo, F. J. Photovoltages exceeding the band gap observed with WSe2/I− solar cells. J. Am. Chem. Soc. 102, 1877 (1980).
Green, M. A. Thin-film solar cells: review of materials, technologies and commercial status. Journal of Materials Science-Materials in Electronics 18, S15–S19 (2007).
Gusakova, J. et al. Electronic Properties of Bulk and Monolayer TMDs: Theoretical Study Within DFT Framework (GVJ-2e Method). Physica Status Solidi (a) 214(12), 1700218 (2017).
Eftekhari, A. Tungsten dichalcogenides (WS2, WSe2, and WTe2): materials chemistry and applications. Journal of Materials Chemistry A 5(35), 18299–18325 (2017).
Kaushalya, P. S., Purohit, A., Chander, S. & Dhaka, M. Thermal annealing evolution to physical properties of ZnS thin films as buffer layer for solar cell applications. Physica E: Low-Dimensional Systems and Nanostructures 101, 174–177 (2018).
Chopra, K. L., Paulson, P. D. & Dutta, V. Thin-film solar cells: An overview. Progress in Photovoltaics, vol. 12, pp. 69–92, (2004)
Sobayel, K. et al. Numerical modeling on prospective buffer layers for tungsten di-sulfide (WS2) solar cells by scaps-1D. Chalcogenide Letters 15(6), 307–315 (2018).
Agrawal, D. et al. Role of low-cost non-toxic MgCl2 treatment on ZnS films: Optimization of physical properties for buffer layers. Optik, 163307 (2019).
Kartopu, G. et al. Enhancement of the photocurrent and efficiency of CdTe solar cells suppressing the front contact reflection using a highly resistive ZnO buffer layer. Solar Energy Materials and Solar Cells 191, 78–82 (2019).
Sharma, R. et al. Physical properties of ZnSe thin films: Air and vacuum annealing evolution to buffer layer applications. Physics Letters A, 126097 (2019).
Wyckoff, R. G. W. Crystal Structures. Inter science, vol 1 (1963).
Jäger-Waldau, A., Lux-Steiner, M. C. & Bucher, E. WS2 thin film: A new candidate for solar cell. Solid State Phenom. 37/38, 479 (1994).
Genut, M., Margulis, L., Hodes, G. & Tenne, R. Preparation and microstructure WS2 thin films. Thin Solid Films 217(1–2), 91–97 (1992).
Rai, A. K., Bhattacharya, R. S., Zabinski, J. S. & Miyoshi, K. A comparison of the wear life of as-deposited and ion-irradiated WS2 coatings. Surf. Coat. Technol. 92, 120 (1997).
Matthäus, A. et al. J. Electrochem. Soc. 144, 1013 (1996).
Ellmer, K., Stock, C., Diesner, K. & Sieber, I. Deposition of c⊥-oriented tungsten disulfide (WS2) films by reactive DC magnetron sputtering from a W-target in Ar/H2S. J. Cryst. Growth 182, 389 (1997).
Ellmer, K., Mientus, R., Seeger, S. & Weiß, V. Reactive magnetron sputtering of tungsten disulfide (WS2−x) films: Influence of deposition parameters on texture, microstructure, and stoichiometry. Phys. stat. sol. (a) 201, p 97 (2004).
Regula, M., Ballif, C. & Lévy, F. Polycrystalline Semiconductors IV – Physics, Chemistry and Technology. Trans Tech, p. 335 (1995).
Martin-litas, I., Vinatier, P., Levasseur, A., Dupin, J. C. & Gonbeau, D. Electrochemical properties of tungsten oxysulfide thin films as positive electrodes for lithium micro-batteries. Thin Films, Volume 26 Issue 7, pp 673–681 (2003).
Sobayel, K. et al. A comprehensive defect study of tungsten disulfide (WS2) as electron transport layer in perovskite solar cells by numerical simulation. Results in Physics, ISSN: 2211–3797, Vol: 12, Page: 1097–1103 (2019).
Seeger, S. et al. Electrical and optical properties of highly (001) textured WSX films deposited by reactive magnetron sputtering. Surf. Coat. Technol. 200 (2005).
Ellmer, K. Low Temperature Plasmas: Fundamentals, Technologies & Techniques. Wiley-VCH, Vol. 2, p. 675 (2008).
Ohsaki, H. & Kokubu, Y. Transparent Conductive Materials: Materials, Synthesis, Characterization. Thin Solid Films 351, 1 (1999).
Islam, M. A. et al. Fabrication of high efficiency sputtered CdS: O/CdTe thin film solar cells from window/absorber layer growth optimization in magnetron sputtering. Solar Energy Materials, vol. 172 (2017).
Chelvanathan, P. et al. Annealing effect in structural and electrical properties of sputtered Mo thin film. Appl. Surf. Sci. (2014).
Nastasi, M., Mayer, J. & Hirvonen, J. K. Ion-Solid Interactions: Fundamentals and Applications. Cambridge Solid State Science Series, Cambridge University Press, Cambridge, UK (2004).
Charles, A. Bishop. Vacuum Deposition onto Webs, Films, and Foils. Elsevier Press, UK (2011).
Vink, T. J., Somers, M. A. J., Daams, J. L. C. & Driks, A. G. Stress, strain, and microstructure in thin tungsten films deposited by dc magnetron sputtering. J. Appl. Phys. 70, 4301 (1991).
Enam, F. M. T. et al. An investigation on structural and electrical properties of close-spaced sublimation grown CdTe thin films in different growth conditions. Chalcogenide Letters, vol. 14 (2017).
Chander, S. & Dhaka, M. S. Thermal evolution of physical properties of vacuum evaporated polycrystalline CdTe thin films for solar cells. J Mater Sci: Mater Electron 27, 11961 (2016).
Scherrer et al. After sixty years: A survey and some new results in the determination of crystallite size. J. Appl. Cryst. 11, p102–113 (1978).
Rashid, A. et al. Structural- and optical-properties analysis of single crystalline hematite (α-Fe2O3) nanocubes prepared by one-pot hydrothermal approach.The Royal Society of Chemistry, issue 25 (2016).
Islam et al. Exploring the Realms of Nature for Nano-synthesis, chapter 3 (2013).
Matare, H. M. Defect electronics in semiconductors, Wiley-Inter science, p-158 (1971).
Dongol, M. et al. Thermal annealing effect on the structural and the optical properties of Nano CdTe films. Optik 126, 1352–1357 (2015).
Tahir, A. A., Wijayantha, K. G. U., Saremi-Yarahmadi, S., Mazhar, M. & McKee, V. Nanostructured α-Fe2O3 Thin Films for Photoelectrochemical Hydrogen Generation. Chemistry of Materials 21(16), 3763–3772 (2009).
Patel, S. L., Chander, S., Purohit, A., Kannan, M. D. & Dhaka, M. S. Influence of NH4Cl treatment on physical properties of CdTe thin films for absorber layer applications, Journal of Physics and Chemistry of Solids (2018).
Chander, S., Purohit, A., Lal, C. & Dhaka, M. S. Enhancement of optical and structural properties of vacuum evaporated CdTe thin films. Materials Chemistry and Physics 185, 202–209 (2017).
Singh, E., Kim, K. S., Yeom, G. Y. & Nalwa, H. S. Two-dimensional transition metal dichalcogenide- based counter electrodes for dye-sensitized solar cells. RSC Adv. 7(45), 28234–28290 (2017).
Goodman, S. A. The characterization of GaAs and AlGaAs by the Hall effect, MSc dissertation, University of Port Elizabeth (1989).
Schroder, D. K. Semiconductor Material and Device Characterization, Arizona State University, Canada (1998).
Stephen, J. Fonash. Solar Cell Device Physics (Second Edition), Pages 1–8 (2010).
Ehemba, A. K., Diallo, D., Ndiaye, A., Socé, M. M. & Dieng, M. The influence of the thickness of the Cds emitter layer on the performance of a CIGS solar cell with acceptor defects. International Journal of Engineering & Applied Sciences (IJEAS). ISSN: 2394–3661, Volume-4, Issue-1 (2017).
Acknowledgements
The authors would like to acknowledge the contribution of The National University of Malaysia through the research grant with code DIP-2019-019. The authors extend their appreciation to the Deanship of Scientific Research at King Saud University for their funding through Research Group no. RGP-1440-116.
Author information
Authors and Affiliations
Contributions
Data collection, experimental works, writing: Md Khan Sobayel Bin Rafiq; Writing & analysis: N. Amin, Md Akhtaruzzaman; Figure & Discussion: Monis Luqman, Afida Ayob; Discussion: Hamad F. Alharbi Badariah Bais, Yahya S. Alharthi, Nabeel Alharthi.
Corresponding authors
Ethics declarations
Competing interests
The authors declare no competing interests.
Additional information
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Bin Rafiq, M.K.S., Amin, N., Alharbi, H.F. et al. WS2: A New Window Layer Material for Solar Cell Application. Sci Rep 10, 771 (2020). https://doi.org/10.1038/s41598-020-57596-5
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/s41598-020-57596-5
This article is cited by
-
Flexible Broadband Solar Plasmonic Absorber Based on Graded Bandgap Multilayer for the Solar Cells Energy Harvesting with High Conversion Efficiency Sensitivity
Plasmonics (2024)
-
All-inorganic perovskite photovoltaics for power conversion efficiency of 31%
Scientific Reports (2023)
-
Efficiency enhancement of silicon-based solar cells by solar energy harvesting in WS2 nano-flake/perovskite layer
Journal of Materials Science: Materials in Electronics (2023)
-
Highly improved light harvesting and photovoltaic performance in CdTe solar cell with functional designed 1D-photonic crystal via light management engineering
Scientific Reports (2022)
-
Performance analysis of n-TiO2/p-Cu2O, n-TiO2/p-WS2/p-Cu2O, and n-TiO2/p-WS2 heterojunction solar cells through numerical modelling
Environmental Science and Pollution Research (2022)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.