Selective reaction of one alcohol among many in complex molecules can be achieved by the use of a catalyst that forms a single covalent bond to a nearby functional group.
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References
Mahatthananchai, J., Dumas, A. M. & Bode, J. W. Angew. Chem. Int. Ed. 51, 10954–10990 (2012).
Sun, X., Lee, H., Lee, S. & Tan, K. L. Nature Chem. 5, 790–795 (2013).
Tan, K. L. ACS Catal. 1, 877–886 (2011).
Pascal, R. Eur. J. Org. Chem. 1813–1824 (2003).
Guimond, N., MacDonald, M. J., Lemieux, V. & Beauchemin, A. M. J. Am. Chem. Soc. 134, 16571–16577 (2012).
Sun, X., Worthy, A. D. & Tan, K. L. Angew. Chem. Int. Ed. 50, 8167–8171 (2011).
Worthy, A. D., Sun, X. & Tan, K. L. J. Am. Chem. Soc. 134, 7321–7324 (2012).
Rousseau, G. & Breit, B. Angew. Chem. Int. Ed. 50, 2450–2494 (2011).
Tan, K. L., Sun, X. & Worthy, A. D. Synlett 23, 312–325 (2012).
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Beauchemin, A. Exploiting intramolecularity. Nature Chem 5, 731–732 (2013). https://doi.org/10.1038/nchem.1737
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DOI: https://doi.org/10.1038/nchem.1737