Abstract
For 50 years the exponential rise in the power of electronics has been fuelled by an increase in the density of silicon complementary metal–oxide–semiconductor (CMOS) transistors and improvements to their logic performance. But silicon transistor scaling is now reaching its limits, threatening to end the microelectronics revolution. Attention is turning to a family of materials that is well placed to address this problem: group III–V compound semiconductors. The outstanding electron transport properties of these materials might be central to the development of the first nanometre-scale logic transistors.
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References
Ferain, I., Colinge, C. A. & Colinge, J.-P. Multigate transistors as the future of classical metal–oxide–semiconductor field-effect transistors. Nature 479, 310–316 (2011).
Chau, R., Doyle, B., Datta, S., Kavalieros, J. & Zhang, K. Integrated nanoelectronics for the future. Nature Mater. 6, 810–812 (2007).
Iwai, H. Roadmap for 22 nm and beyond. Microelectron. Eng. 86, 1520–1528 (2009).
Frank, D. J. Power-constrained CMOS scaling limits. IBM J. Res. Dev. 46, 235–244 (2002).
Theis, T. N. & Solomon, P. M. In quest of the “next switch”: prospects for greatly reduced power dissipation in a successor to the silicon field-effect transistor. Proc. IEEE 98, 2005–2014 (2010).
del Alamo, J. A. The high-electron mobility transistor at 30: impressive accomplishments and exciting prospects. Int. Conf. Compound Semicond. Manuf. Technol. 17–22 (CS ManTech, 2011).
ITRS, International Technology Working Groups International Technology Roadmap for Semiconductors 〈http://www.itrs.net/Links/2010ITRS/Home2010.htm〉 (ITRS, 2010).
Kim, D.-H. et al. 50-nm E-mode In0.7Ga0.3As PHEMTs on 100-mm InP substrate with f max > 1 THz. IEEE Int. Electron Devices Meet. 692–695 (IEEE, 2010).
Kim, D.-H. & del Alamo, J. A. 30-nm InAs PHEMTs With f T = 644 GHz and f max = 681 GHz. IEEE Electron Device Lett. 31, 806–808 (2010).
Leuther, A. et al. 20 nm Metamorphic HEMT with 660 GHz f T. Int. Conf. Indium Phosphide Relat. Mater. (IEEE, 2011).
Jeong, C., Antoniadis, D. A. & Lundstrom, M. S. On backscattering and mobility in nanoscale silicon MOSFETs. IEEE Trans. Electron Devices 56, 2762–2769 (2009).
del Alamo, J. A., Kim, D.-H., Kim, T.-W., Jin, D. & Antoniadis, D. A. III–V CMOS: what have we learned from HEMTs? Int. Conf. Indium Phosphide Relat. Mater. (IEEE, 2011).
Kim, D. H., del Alamo, J. A., Antoniadis, D. A. & Brar, B. Extraction of virtual-source injection velocity in sub-100 nm III–V HFETs. IEEE Int. Electron Devices Meet. 861–864 (IEEE, 2009). This paper reports that the electron injection velocity in InGaAs and InAs HEMTs is more than double that in Si MOSFETs of similar gate length at half the voltage.
Khakifirooz, A. & Antoniadis, D. A. MOSFET performance scaling — part I: historical trends. IEEE Trans. Electron Devices 55, 1391–1400 (2008).
Liu, Y. et al. in Fundamentals of III–V Semiconductor MOSFETs (eds Oktyabrsky, S. & Ye, P. D.) 31–50 (Springer, 2010).
Fischetti, M. V. & Laux, S. E. Are GaAs MOSFETs worth building? A model-based comparison of Si and GaAs n-MOSFETs. IEEE Int. Electron Devices Meet. 481–484 (IEEE, 1989).
Jin, D., Kim, D.-H., Kim, T. & del Alamo, J. A. Quantum capacitance in scaled down III–V FETs. IEEE Int. Electron Devices Meet. 495–498 (IEEE, 2009).
Kim, T.-W., Kim, D.-H. & del Alamo, J. A. Logic characteristics of 40 nm thin-channel InAs HEMTs. Int. Conf. Indium Phosphide Relat. Mater. 496–499 (IEEE, 2010).
Kim, T.-W. & del Alamo, J. A. Injection velocity in thin-channel InAs HEMTs. Int. Conf. Indium Phosphide Relat. Mater. (IEEE, 2011).
Kim, D.-H. & del Alamo, J. A. 30 nm E-mode InAs PHEMTs for THz and future logic applications. IEEE Int. Electron Devices Meet. 719–722 (IEEE, 2008).
Dewey, G. et al. Logic performance evaluation and transport physics of Schottky-gate III–V compound semiconductor quantum well field effect transistors for power supply voltages (V CC) ranging from 0.5 V to 1.0 V. IEEE Int. Electron Devices Meet. 487–490 (IEEE, 2009).
Umansky, V. et al. MBE growth of ultra-low disorder 2DEG with mobility exceeding 35 × 106 cm2/Vs. J. Cryst. Growth 311, 1658–1661 (2009).
Spicer, W. E., Lindau, I., Skeath, P. & Su, C. Y. Unified defect model and beyond. J. Vac. Sci. Technol. 17, 1019–1027 (1980).
Hinkle, C. L. et al. GaAs interfacial self-cleaning by atomic layer deposition. Appl. Phys. Lett. 92, 071901 (2008).
Scarrozza, M. et al. A theoretical study of the initial oxidation of the GaAs(001)-β2(2×4) surface. Appl. Phys. Lett. 95, 253504 (2009).
Becke, H., Hall, R. & White, J. Gallium arsenide MOS transistors. Solid State Electron. 8, 813–818 (1965).
Mimura, T., Odani, K., Yokoyama, N., Nakayama, Y. & Fukuta, M. GaAs microwave MOSFETs. IEEE Trans. Electron Devices 25, 573–579 (1978).
Passlack, M. et al. In-situ Ga203 process for GaAs inversion/accumulation device and surface passivation applications. IEEE Int. Electron Devices Meet. 383–386 (IEEE, 1995).
Passlack, M., Hong, M. & Mannaerts, J. P. Quasistatic and high frequency capacitance–voltage characterization of Ga2O3–GaAs structures fabricated by in situ molecular beam epitaxy. Appl. Phys. Lett. 68, 1099–1101 (1996).
Passlack, M., Hong, M., Mannaerts, J. P., Kwo, J. R. & Tu, L. W. Recombination velocity at oxide–GaAs interfaces fabricated by in situ molecular beam epitaxy. Appl. Phys. Lett. 68, 3605–3607 (IEEE, 1996).
Ren, F. et al. Enhancement-mode p-channel GaAs MOSFETs on semi-insulating substrates. IEEE Int. Electron Devices Meet. 943–945 (IEEE, 1996).
Ren, F. et al. Demonstration of enhancement-mode p- and n-channel GaAs MOSFETS with Ga2O3(Gd2O3) As gate oxide. Solid State Electron. 41, 1751–1753 (1997).
Ye, P. D. et al. GaAs MOSFET with oxide gate dielectric grown by atomic layer deposition. IEEE Electron Device Lett. 24, 209–211 (2003).
Frank, M. M. et al. HfO2 and Al2O3 gate dielectrics on GaAs grown by atomic layer deposition. Appl. Phys. Lett. 86, 152904 (2005).
Huang, M. L. et al. Surface passivation of III–V compound semiconductors using atomic-layer-deposition-grown Al2O3 . Appl. Phys. Lett. 87, 252104 (2005).
Milojevic, M. et al. Half-cycle atomic layer deposition reaction studies of Al2O3 on (NH4)2S passivated GaAs(100) surfaces. Appl. Phys. Lett. 93, 252905 (2008).
Xuan, Y., Lin, H. C., Ye, P. D. & Wilk, G. D. Capacitance–voltage studies on enhancement-mode InGaAs metal-oxide-semiconductor field-effect transistor using atomic-layer-deposited Al2O3 gate dielectric. Appl. Phys. Lett. 88, 263518 (2006).
Li, N. et al. Properties of InAs metal-oxide-semiconductor structures with atomic-layer-deposited Al2O3 dielectric. Appl. Phys. Lett. 92, 143507 (2008).
Wu, Y. Q., Xuan, Y., Ye, P. D., Cheng, Z. & Lochtefeld, A. Inversion-type enhancement-mode InP MOSFETs with ALD Al2O3, HfO2 and HfAlO nanolaminates as high-κ gate dielectrics. IEEE Device Res. Conf. 117–118 (IEEE, 2007).
Wang, W., Xiong, K., Wallace, R. M. & Cho, K. Impact of interfacial oxygen content on bonding, stability, band offsets, and interface states of GaAs:HfO2 interfaces. J. Phys. Chem. C 114, 22610–22618 (2010).
Lin, L. & Robertson, J. Defect states at III–V semiconductor oxide interfaces. Appl. Phys. Lett. 98, 082903 (2011). This paper provides density-functional theory calculations of interface defect states between high- κ oxides and GaAs, InAs and InP that are consistent with experimental observation.
Wang, W., Lee, G., Huang, M., Wallace, R. M. & Cho, K. First-principles study of GaAs(001)-β2(2×4) surface oxidation and passivation with H, Cl, S, F, and GaO. J. Appl. Phys. 107, 103720 (2010).
Passlack, M., Droopad, R. & Brammertz, G. Suitability study of oxide/gallium arsenide interfaces for MOSFET applications. IEEE Trans. Electron Devices 57, 2944–2956 (2010). This experimental study of oxide–GaAs interfaces for MOSFET applications finds that whereas in situ -deposited Ga 2 O 3 leads to excellent interfacial quality, ex situ ALD-deposited Al 2 O 3 on GaAs leads to Fermi-level pinning.
Trinh, H. D. et al. The influences of surface treatment and gas annealing conditions on the inversion behaviors of the atomic-layer-deposition Al2O3/n-In0.53Ga0.47As metal-oxide-semiconductor capacitor. Appl. Phys. Lett. 97, 042903 (2010).
O'Connor, E. et al. A systematic study of (NH4)2S passivation (22%, 10%, 5%, or 1%) on the interface properties of the Al2O3/In0.53Ga0.47As/InP system for n-type and p-type In0.53Ga0.47As epitaxial layers. J. Appl. Phys. 109, 024101 (2011).
Ok, I. & Lee, J. C. in Fundamentals of III–V Semiconductor MOSFETs (eds Oktyabrsky, S. & Ye, P. D.) 307–348 (Springer, 2010).
Wu, Y. D. et al. Engineering of threshold voltages in molecular beam epitaxy-grown Al2O3/Ga2O3(Gd2O3)/In0.2Ga0.8As. J. Vac. Sci. Technol. B 28, C3H10–C3H13 (2010).
Cheng, C.-W., Apostolopoulos, G. & Fitzgerald, E. A. The effect of interface processing on the distribution of interfacial defect states and the C–V characteristics of III–V metal-oxide-semiconductor field effect transistors. J. Appl. Phys. 109, 023714 (2011).
Chen, Y.-T. et al. Fluorinated HfO2 gate dielectric engineering on In0.53Ga0.47As metal-oxide-semiconductor field-effect-transistors. Appl. Phys. Lett. 96, 103506 (2010).
Engel-Herbert, R., Hwang, Y., Cagnon, J. l. & Stemmer, S. Metal-oxide-semiconductor capacitors with ZrO2 dielectrics grown on In0.53Ga0.47As by chemical beam deposition. Appl. Phys. Lett. 95, 062908 (2009).
Liu, Y., Xu, M., Heo, J., Ye, P. D. & Gordon, R. G. Heteroepitaxy of single-crystal LaLuO3 on GaAs(111)A by atomic layer deposition. Appl. Phys. Lett. 97, 162910 (2010).
Xu, M. et al. New insight into Fermi-level unpinning on GaAs: impact of different surface orientations. IEEE Int. Electron Devices Meet. 865–868 (IEEE, 2009).
Ishii, H. et al. High electron mobility metal–insulator–semiconductor field-effect transistors fabricated on (111)-oriented InGaAs channels. Appl. Phys. Express 2, 121101 (2009).
Wang, C., Xu, M., Colby, R., Stach, E. A. & Ye, P. D. “Zero” drain-current drift of inversion-mode NMOSFET on InP (111)A surface. IEEE Device Res. Conf. 93–94 (IEEE, 2011).
Ye, P. D., Xuan, Y., Wu, Y. Q. & Xu, M. Inversion-mode InxGa1−xAs MOSFETs (x = 53, 65, 75) with atomic-layer-deposited high-κ dielectrics. ECS Trans. 19, 605–614 (2009). This paper reports significant improvements in ALD oxide InGaAs MOSFET transistor characteristics as the InAs mole fraction in the channel is increased.
Sonnet, A. M. et al. On the calculation of effective electric field in In0.53Ga0.47As surface channel metal-oxide-semiconductor field-effect-transistors. Appl. Phys. Lett. 98, 193501 (2011).
Sonnet, A. M. et al. Remote phonon and surface roughness limited universal electron mobility of In0.53Ga0.47As surface channel MOSFETs. Microelectron. Eng. 88, 1083–1086 (2011).
Oktyabrsky, S. et al. Electron scattering in buried InGaAs/high-κ MOS channels. ECS Trans. 35, 385–395 (2011).
Radosavljevic, M. et al. Advanced high-κ gate dielectric for high-performance short-channel In0.7Ga0.3As quantum well field effect transistors on silicon substrate for low power logic applications. IEEE Int. Electron Devices Meet. 319–322 (IEEE, 2009). This paper reports the best logic performance of a III–V MOSFET so far, exceeding that of state-of-the-art silicon MOSFETs at 0.5 V.
Kuhn, K. J., Liu, M. Y. & Kennel, H. Technology options for 22 nm and beyond. Int. Workshop Junct. Technol. 1–6 (IEEE, 2010).
Waldron, N., Kim, D.-H. & del Alamo, J. A. A self-aligned InGaAs HEMT architecture for logic applications. IEEE Trans. Electron Devices 57, 297–304 (2010).
Kim, T.-W., Kim, D.-H. & del Alamo, J. A. 60 nm Self-aligned-gate InGaAs HEMTs with record high-frequency characteristics. IEEE Int. Electron Devices Meet. 696–699 (IEEE, 2010).
Singisetti, U. et al. Ultralow resistance in situ ohmic contacts to InGaAs/InP. Appl. Phys. Lett. 93, 183502 (2008). This paper reports Mo/n+–InGaAs ohmic contacts with contact resistance comparable to state-of-the-art silicon technology.
Chin, H.-C., Gong, X., Liu, X. & Yeo, Y. Lattice-mismatched In0.4Ga0.6As source/drain stressors with in situ doping for strained In0.53Ga0.47As channel n-MOSFETs. IEEE Electron Device Lett. 30, 805–807 (2009).
Terao, R. et al. InP/InGaAs composite metal–oxide–semiconductor field-effect transistors with regrown source and Al2O3 gate dielectric exhibiting maximum drain current exceeding 1.3 mA/μm. Appl. Phys. Express 4, 054201 (2011). This paper reports that a 100-nm gate length InGaAs MOSFET with raised epitaxially grown source and drain regions has excellent electrical characteristics.
Doyle, B. S. et al. High performance fully-depleted tri-gate CMOS transistors. IEEE Electron Device Lett. 24, 263–265 (2003).
Wu, Y. Q., Xu, M., Wang, R. S., Koybasi, O. & Ye, P. D. High performance deep-submicron inversion-mode InGaAs MOSFETs with maximum G m exceeding 1.1 mS/μm: new HBr pretreatment and channel engineering. IEEE Int. Electron Devices Meet. 323–326 (IEEE, 2009).
Radosavljevic, M. et al. Non-planar, multi-gate InGaAs quantum well field effect transistors with high-κ gate dielectric and ultra-scaled gate-to-drain/gate-to-source separation for low power logic applications. IEEE Int. Electron Devices Meet. 126–129 (IEEE, 2010).
Pearton, S. J. & Norton, D. P. Dry etching of electronic oxides, polymers, and semiconductors. Plasma Process. Polym. 2, 16–37 (2005).
Hashemi, P., Gomez, L., Canonico, M. & Hoyt, J. L. Electron transport in gate-all-around uniaxial tensile strained-Si nanowire n-MOSFETs. IEEE Int. Electron Devices Meet. 1–14 (IEEE, 2008).
Suk, S. D. et al. High performance 5nm radius twin silicon nanowire MOSFET (TSNWFET): fabrication on bulk Si wafer, characteristics, and reliability. IEEE Int. Electron Devices Meet. 717–720 (IEEE, 2005).
Do, Q. T., Blekker, K., Regolin, I., Prost, W. & Tegude, F. J. Single n-InAs nanowire MIS-field-effect transistor: experimental and simulation results. IEEE Int. Indium Phosphide Relat. Mater. 392–395 (IEEE, 2007).
Egard, M. et al. Vertical InAs nanowire wrap gate transistors with f t > 7 GHz and f max > 20 GHz. Nano Lett. 10, 809–812 (2010).
Hock, G., Hackbarth, T., Erben, U., Kohn, E. & Konig, U. High performance 0.25 μm p-type Ge/SiGe MODFETs. Electron. Lett. 34, 1888–1889 (1998).
Bennett, B. R., Ancona, M. G., Boos, J. B. & Shanabrook, B. V. Mobility enhancement in strained p-InGaSb quantum wells. Appl. Phys. Lett. 91, 042104 (2007).
Bennett, B., Ancona, M., Boos, J., Canedy, C. & Khan, S. Strained GaSb/AlAsSb quantum wells for p-channel field-effect transistors. J. Cryst. Growth 311, 47–53 (2008).
Radosavljevic, M. et al. High-performance 40 nm gate length InSb p-channel compressively strained quantum well field effect transistors for low-power (V CC = 0.5 V) logic applications. IEEE Int. Electron Devices Meet. 1–4 (IEEE, 2008).
Kuhn, K. J., Murthy, A., Kotlyar, R. & Kuhn, M. Past, present and future: SiGe and CMOS transistor scaling. ECS Trans. 33, 3–17 (2010).
Xia, L., Boos, J. B., Bennett, B. R., Ancona, M. G. & del Alamo, J. A. Hole mobility enhancement in In0.41Ga0.59Sb quantum-well field-effect transistors. Appl. Phys. Lett. 98, 053505 (2011).
Xia, L. V. T., Oktyabrsky, S. & del Alamo, J. A. Mobility enhancement of two-dimensional hole Gas in an In0.24Ga0.76As quantum well by <110> uniaxial strain. Int. Symp. Compound Semicond. 2011 (IEEE, in the press).
Nainani, A. et al. Engineering of strained III–V heterostructures for high hole mobility. IEEE Int. Electron Devices Meet. 857–860 (IEEE, 2009).
Gomez, L., Chleirigh, C. N., Hashemi, P. & Hoyt, J. L. Enhanced hole mobility in high Ge content asymmetrically strained-SiGe p-MOSFETs. IEEE Electron Device Lett. 31, 782–784 (2010).
Passlack, M. et al. Self-aligned GaAs p-channel enhancement mode MOS heterostructure field-effect transistor. IEEE Electron Device Lett. 23, 508–510 (2002).
Nainani, A. et al. Development of high-κ dielectric for antimonides and a sub 350 °C III–V pMOSFET outperforming germanium. IEEE Int. Electron Devices Meet. 138–141 (IEEE, 2010). This paper describes p-type InGaSb MOSFETs with an ALD Al 2 O 3 gate dielectric and excellent characteristics.
Pillarisetty, R. et al. High mobility strained germanium quantum well field effect transistor as the p-channel device option for low power (V cc = 0.5 V) III–V CMOS architecture. IEEE Int. Electron Devices Meet. 150–153 (IEEE, 2010).
Nakwaski, W. Thermal conductivity of binary, ternary, and quaternary III–V compounds. J. Appl. Phys. 64, 159–166 (1988).
Hudait, M. K. et al. Heterogeneous integration of enhancement mode In0.7Ga0.3As quantum well transistor on silicon substrate using thin (≤ 2 μm) composite buffer architecture for high-speed and low-voltage (0.5 V) logic applications. IEEE Int. Electron Devices Meet. 625–628 (2007).
Tang, C. W., Li, H., Zhong, Z., Ng, K. L. & Lau, K. M. Hetero-epitaxy of III–V compounds lattice-matched to InP by MOCVD for device applications. IEEE Int. Conf. Indium Phosphide Relat. Mater. 136–139 (IEEE, 2009).
Yokoyama, M. et al. Extremely-thin-body InGaAs-on-insulator MOSFETs on Si fabricated by direct wafer bonding. IEEE Int. Electron Devices Meet. 46–49 (2010).
Ko, H. et al. Ultrathin compound semiconductor on insulator layers for high-performance nanoscale transistors. Nature 468, 286–289 (2010). This paper reports on thin-channel InAs-on-insulator MOSFETs with excellent electrical characteristics fabricated on a silicon substrate by a layer-transfer process.
Fang, H. et al. Strain engineering of epitaxially transferred, ultrathin layers of III–V semiconductor on insulator. Appl. Phys. Lett. 98, 012111 (2011).
Fiorenza, J. et al. Aspect ratio trapping: a unique technology for integrating Ge and III–Vs with silicon CMOS. ECS Trans. 33, 963–976 (2010).
Wu, Y. Q. et al. Atomic-layer-deposited Al2O3/GaAs metal-oxide-semiconductor field-effect transistor on Si substrate using aspect ratio trapping technique. Appl. Phys. Lett. 93, 242106 (2008).
Moore, G. E. Cramming more components onto integrated circuits. Electronics 38, 114–117 (1965).
Hutcheson, G. D. in Into the Nano Era: Moore's Law Beyond Planar Silicon CMOS (ed. Huff, H.) 11–38 (Springer, 2009).
Acknowledgements
I have enjoyed stimulating discussions with students, collaborators and colleagues. I am particularly thankful to D. Antoniadis, R. Chau, S. Datta, J. Hoyt, D. Jin, D.-H. Kim, T.-W. Kim, A. Kummel, J. Lin, M. Lundstrom, S. Oktyabrsky, M. Passlack, M. Radosavljevic, E. Vogel, N. Waldron, R. Wallace, L. Xia and P. Ye. Research on III–V CMOS transistors at my lab at MIT has been funded by the Materials, Structures and Devices FCRP Center and Intel Corporation.
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del Alamo, J. Nanometre-scale electronics with III–V compound semiconductors. Nature 479, 317–323 (2011). https://doi.org/10.1038/nature10677
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DOI: https://doi.org/10.1038/nature10677
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