Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Brief Communication
  • Published:

Materials

Carbon nanotubes in an ancient Damascus sabre

Abstract

The steel of Damascus blades, which were first encountered by the Crusaders when fighting against Muslims, had features not found in European steels — a characteristic wavy banding pattern known as damask, extraordinary mechanical properties, and an exceptionally sharp cutting edge. Here we use high-resolution transmission electron microscopy to examine a sample of Damascus sabre steel from the seventeenth century and find that it contains carbon nanotubes as well as cementite nanowires. This microstructure may offer insight into the beautiful banding pattern of the ultrahigh-carbon steel created from an ancient recipe that was lost long ago.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: High-resolution transmission electron microscopy images of carbon nanotubes in a genuine Damascus sabre after dissolution in hydrochloric acid.

Similar content being viewed by others

References

  1. Wadsworth, J. MRS Bull. 27, 980–987 (2002).

    Article  CAS  Google Scholar 

  2. Verhoeven, J. D. Steel Res. 73, 356–365 (2002).

    Article  CAS  Google Scholar 

  3. Kochmann, W. et al. J. Alloys Comp. 372, L15–L19 (2004).

    Article  CAS  Google Scholar 

  4. Levin, A. A. et al. Crystal Res. Technol. 40, 905–916 (2005).

    Article  ADS  CAS  Google Scholar 

  5. Reibold, M., Levin, A. A., Meyer, D. C., Paufler, P. & Kochmann, W. Int. J. Mater. Res. 97, 1172–1182 (2006).

    Article  CAS  Google Scholar 

  6. Zschokke, B. Rev. Métallurg. 21, 635–669 (1924).

    Article  CAS  Google Scholar 

  7. Golberg, D. et al. Acta Mater. 54, 2567–2576 (2006).

    Article  CAS  Google Scholar 

  8. Ni, L. et al. Carbon 44, 2265–2272 (2006).

    Article  CAS  Google Scholar 

  9. Chernozatonskii, L. A. et al. Carbon 35, 749–753 (1997).

    Article  CAS  Google Scholar 

  10. Schwarz, C. Stahl u. Eisen 21, 209–211 (1901).

    Google Scholar 

  11. Verhoeven, J. D., Pendray, A. H. & Dauksch, W. JOM 56, 17–20 (2004).

    Article  CAS  Google Scholar 

  12. He, C., Zhao, N., Shi, C., Du, X. & Li, J. Mater. Chem. Phys. 97, 109–115 (2006).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to P. Paufler.

Supplementary information

Rights and permissions

Reprints and permissions

About this article

Cite this article

Reibold, M., Paufler, P., Levin, A. et al. Carbon nanotubes in an ancient Damascus sabre. Nature 444, 286 (2006). https://doi.org/10.1038/444286a

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/444286a

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing