Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Fractal patterns from chemical dissolution

Abstract

The highly ramified patterns1,2 produced by the flow of a reactive fluid through a soluble porous medium have never been quantitatively described. The theoretical understanding of this phenomenon is limited to very simple conditions (such as the flow of a liquid through a; capillary3) due to the complexity of the coupling between the chemical reaction and the fluid flow. We show here that the dissolution patterns (DP) obtained experimentally by injecting water through pure plaster are fractal, for different geometries of the samples. In two dimensions, these DP are remarkably'similar to patterns associated with diffusion-limited aggregation4–6 (DLA), that is, dielectric breakdown7, viscous fingering8,9 and diffusion-limited polymerization10. In three dimensions, we compare them with DLA clusters grown in the same boundary conditions and find a good qualitative and quantitative similarity. These results should be of interest in different areas where chemical dissolution of porous media by a flowing fluid occurs, for example, in nature (the formation of caves) and in industry (in the oil industry where acids are routinely injected into oil reservoirs).

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Ewers, R. O. Thesis, McMaster Univ., Hamilton. Ontario (1982).

  2. Lee, P. B. & Mason, G. I. Chem. E. Jubilee Symp. Ser. 73, A13–21 (1982).

    CAS  Google Scholar 

  3. Levich, V. G. in Physicochemical Hydrodynamics (ed. Scriven, L. E.) 112–16 (Prentice-Hall, Englewoods Cliffs, 1962).

    Google Scholar 

  4. Witten, T. A. & Sander, L. M. Phys. Rev. Lett. 47, 1499–1501 (1981).

    Article  Google Scholar 

  5. Witten, T. A. & Sander, L. M. Phys. Rev. Lett. B27, 5685–5697 (1983).

    ADS  Google Scholar 

  6. Meaking, P. Phys. Rev. A27, 604–607 (1983).

    Article  ADS  Google Scholar 

  7. Niemeyer, L., Pietronero, L. & Weismann, H. J. Phys. Rev. Lett. 52, 1033–1036 (1984).

    Article  ADS  Google Scholar 

  8. Måløy, K. J., Feder, J. & Jøssang, T. Phys. Rev. Lett. 55, 1885–1891 (1985).

    Article  Google Scholar 

  9. Daccord, G., Nittmann, J. & Stanley, H. E. Phys. Rev. Lett. 56, 336–339 (1986).

    Article  ADS  CAS  Google Scholar 

  10. Kaufman, J. H. et al. Phys. Rev. Lett. 56, 1932–1935 (1986).

    Article  ADS  CAS  Google Scholar 

  11. Brady, R. M. & Ball, R. C. Nature 309, 225–229 (1984).

    Article  ADS  CAS  Google Scholar 

  12. Meakin, P. Phys. Rev. A27, 2616–2623 (1983).

    Article  ADS  Google Scholar 

  13. Rácz, Z. & Vicsek, T. Phys. Rev. Lett. 51, 2382–2385 (1983).

    Article  ADS  Google Scholar 

  14. Meakin, P. Phys. Rev. B30, 4207–4214 (1984).

    Article  ADS  Google Scholar 

  15. Nittmann, J., Daccord, G. & Stanley, H. E. Nature 314, 141–144 (1985).

    Article  ADS  CAS  Google Scholar 

  16. Hentschel, H. G. E. & Deutsch, J. M. Preprint (Massachusetts Insitute of Technology, 1986).

  17. Daccord, G. Phys. Rev. Lett. (in the press).

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Daccord, G., Lenormand, R. Fractal patterns from chemical dissolution. Nature 325, 41–43 (1987). https://doi.org/10.1038/325041a0

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1038/325041a0

This article is cited by

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing