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Alkali Metal Complexation. Binding Properties of cone and partial-cone Calix[4]arenes Bearing a Mixed (O 2 , O 2 ') Donor Set (O = Phosphine Oxide; O ' = Amide or Ester)

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Abstract

The stability constants of alkali metal complexes obtained from the followingO-substituted calix[4]arenes were determined by UV/Vis spectroscopy inmethanol at 20°C: 5,11,17,23-tetra-tert-butyl-25,27-bis(diethylcarbamoylmethoxy)-26,28-bis(diphenylphosphinoylmethoxy)calix[4]arene(cone-1), 25,27-syn-26,28-anti-5,11,17,23-tetra-tert-butyl-25,27-bis(diethylcarbamoylmethoxy)-26,28-bis(diphenylphosphinoylmethoxy)calix[4]arene (paco-1),5,11,17,23-tetra-tert-butyl-25,27-diethoxycarbonylmethoxy-26,28-bis(diphenylphosphinoylmethoxy)calix[4]arene(cone-2) and25,27-syn-26,28-anti-5,11,17,23-tetra-tert-butyl-25,27-diethoxycarbonylmethoxy-26,28-bis(diphenylphosphinoylmethoxy)calix[4]arene(paco-2). All ligands form 1:1 complexes with alkali metal cations. The amide-containing calixarenes were found to be more efficient for alkali metalcomplexation than those bearing ester substituents. While sodium ions are selectivelycomplexed by the two mixed amide-(phosphine oxide) calixarenes, the twoester-containing isomers cone-2 and paco-2 turned out to be selective towards potassium and rubidium ions, respectively. With allfour ligands the lowest stability constants were found for the lithium andcesium ions.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Zanjan University, P.O. Box 45195/313, Zanjan, Iran

    M.R. Yaftian & M. Vahedpour

  2. Department of Chemistry, Institute for Advanced Studies in Basic Sciences, Zanjan, Iran

    H. Abdollahi

  3. Laboratoire de Chimie Inorganique Moléculaire, UMR 7513 CNRS, Université Louis Pasteur, 1 rue Blaise Pascal, 67008, Strasbourg, France

    C. Jeunesse & D. Matt

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  1. M.R. Yaftian
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  2. M. Vahedpour
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  4. C. Jeunesse
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Yaftian, M., Vahedpour, M., Abdollahi, H. et al. Alkali Metal Complexation. Binding Properties of cone and partial-cone Calix[4]arenes Bearing a Mixed (O 2 , O 2 ') Donor Set (O = Phosphine Oxide; O ' = Amide or Ester). Journal of Inclusion Phenomena 47, 129–132 (2003). https://doi.org/10.1023/B:JIPH.0000011782.54437.11

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  • DOI: https://doi.org/10.1023/B:JIPH.0000011782.54437.11

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