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Characterization of the coordination network formed on self-assembly of 1,2-bis(3′-pyridyl)ethyne with copper(I) iodide

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Abstract

The self-assembly of 1,2-bis(3′-pyridyl)ethyne with copper(I) iodide is described. The X-ray crystal structure of the resultant pale yellow crystalline solid reveals that the sheets of the two-dimensional coordination network are stacked such that channels are formed. The structure (C12H8Cu2I2N2) is monoclinic with a = 9.285(2) Å, b = 4.1502(9) Å, c = 22.096(5) Å, β = 97.380(11)°, and space group P2 1/c.

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Authors and Affiliations

  1. Chemistry Department, Southwest Missouri State University, Springfield, Missouri, 65804

    Eric Bosch

  2. Chemistry Department, University of Arkansas, Fayetteville, Arkansas, 72701

    Wally Cordes

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  1. Eric Bosch
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  2. Wally Cordes
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Correspondence to Eric Bosch.

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Bosch, E., Cordes, W. Characterization of the coordination network formed on self-assembly of 1,2-bis(3′-pyridyl)ethyne with copper(I) iodide. Journal of Chemical Crystallography 33, 723–726 (2003). https://doi.org/10.1023/A:1026199105648

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