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Spectrophotometric Study of the Complexation of Some Lanthanide (III) Ions with a Series of 18-Crowns-6 in DMSO Solution Using Murexide as a Metallochromic Indicator

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Abstract

The complexation of La(III), Ce(III), Pr(III) and Er(III) with 18-crown-6(18C6), dibenzo-18-crown-6 (DB18C6), dicyclohexano-18-crown-6 (DCY18C6) anddibenzopyridino-18-crown-6 (DBPY18C6) has been studied in dimethylsulfoxide(DMSO) by means of a competitive spectrophotometric method using murexide asa metal ion indicator. The formation constants of the 1 : 1 complexeswere found tovary in the order La(III) > Ce(III) > Pr(III) > Er(III). It was foundthat the structure influences the formation and stability of the resultingcomplexes. The effects ofvarious parameters on complexation are discussed. The order of the stabilityconstants of each lanthanide ion with these macrocycles are18C6 > DC18C6 > DB18C6 > DBPY18C6.

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Authors and Affiliations

  1. Department of Chemistry, University of Arak, P.O. Box 38156-879, Arak, Iran

    Javad Zolgharnein, Fariborz Riahii & Saeid Amani

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  1. Javad Zolgharnein
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  2. Fariborz Riahii
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  3. Saeid Amani
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Zolgharnein, J., Riahii, F. & Amani, S. Spectrophotometric Study of the Complexation of Some Lanthanide (III) Ions with a Series of 18-Crowns-6 in DMSO Solution Using Murexide as a Metallochromic Indicator. Journal of Inclusion Phenomena 45, 13–17 (2003). https://doi.org/10.1023/A:1023001331866

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