Skip to main content
Log in

Thermodynamic characteristics of supramolecular complexes of aroma compounds with ordered structures of polysaccharides of corn starch and its cryotextures

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Supramolecular complexes of organic odorants (n-octanol and n-octyl acetate) with polysaccharides of corn starch, its cryotextures, and waxy corn starch cryotextures were studied by differential scanning microcalorimetry. It was shown that complexes are formed with amylose-containing starch and no complexes are formed with amylopectin starch. The melting enthalpies of the complexes were determined. It was shown that complexes of the odorants with native corn starch and its cryotextures have different thermodynamic characteristics.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Jean-Marie Lehn, Supramolecular Chemistry. Concepts and Perspectives, Weinheim, New York.

  2. F. W. Lichtenthaler and S. Immel, Tetrahedron Asymmetry, 1994, 5, 2045.

    Google Scholar 

  3. S. Kubik, O. Holler, A. Steinert, and W. Wulff, Macromol. Synth., 1995, 99, 93.

    Google Scholar 

  4. S. Kubik, O. Holler, A. Steinert, M. Tolksdorf, Y. van der Leek, and W. Wulff, in Carbohydrates as Organic Raw Materials, Eds. H. van Bekkum, H. Roper, and F. Voragen, VCH, Weinheim, 1996, 3, 169.

    Google Scholar 

  5. G. Wulff and S. Kubik, Macromol. Chem., 1992, 193, 1071.

    Google Scholar 

  6. F. Osman-Ismail and J. Solms, Lebensm. Wiss. Technol., 1973, 6, 147.

    Google Scholar 

  7. M. Kowblannsky, Macromolecules, 1985, 18, 1776.

    Google Scholar 

  8. R. V. Golovnya and T. A. Misharina, Izv. Akad. Nauk, Ser. Khim., 1998, 310 [Russ. Chem. Bull., 1998, 47, 303 (Engl. Transl.)].

  9. R. V. Golovnya, T. A. Misharina, and M. B. Terenina, Nahrung, 1999, 42, 380.

    Google Scholar 

  10. T. A. Misharina, N. I. Krikunova, and R. V. Golovnya, Izv. Akad. Nauk, Ser. Khim., 1998, 1943 [Russ. Chem. Bull., 1998, 47, 1889 (Engl. Transl.)].

  11. M. B. Terenina, T. A. Misharina, and R. V. Golovnya, Izv. Akad. Nauk, Ser. Khim., 1998, 730 [Russ. Chem. Bull., 1998, 48, 734 (Engl. Transl.)].

    Google Scholar 

  12. T. A. Misharina, M. B. Terenina, N. I. Krikunova, I. B. Medvedeva, and R. V. Golovnya, Izv. Akad. Nauk, Ser. Khim., 1999, 1496 [Russ. Chem. Bull., 1999, 48, 1478 (Engl. Transl.)].

    Google Scholar 

  13. A. G. Filatova, I. O. Volkov, N. I. Krikunova, T. A. Misharina, and R. V. Golovnya, Izv. Akad. Nauk, Ser. Khim., 2000, 312 [Russ. Chem. Bull., Int. Ed., 2000, 49, 314].

    Google Scholar 

  14. A. N. Danilenko, E. V. Shtykov, and V. P. Yur'ev, Biofizika, 1994, 39, 442 [Biophysics, 1994, 39, 427 (Engl. Transl.)].

    Google Scholar 

  15. V. P. Yur'ev, A. N. Danilenko, and I. E. Nemirovskaya, Biofizika, 1997, 42, 129 [Biophysics, 1997, 42, 135 (Engl. Transl.)].

    Google Scholar 

  16. V. P. Yur'ev, A. N. Danilenko, I. E. Nemirovskaya, N. D. Lukin, A. I. Zhushman, and V. G. Karpov, Prikladnaya Biokhimiya i Mikrobiologiya, 1996, 32, 571 [Appl. Biochem., Microbiol., 1996, 32, 514 (Engl. Transl.)].

    Google Scholar 

  17. C. G. Biliaderis, Food Technol., 1992, 46, 98.

    Google Scholar 

  18. Yu. I. Matveev, N. Yu. Elankin, E. N. Kakistrova, A. N. Danilenko, C. Niemann, and V. P. Yuryev, Starch, 1998, 50, 141.

    Google Scholar 

  19. S. Hizukuri, Carbohydr. Res., 1986, 147, 342.

    Google Scholar 

  20. J. J. G. van Soest, D. de Wit, H. Tournois, and J. F. G. Vliegenthart, Starch/Starke, 1994, 46, 453.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Golovnya, R.V., Yuryev, V.P., Kalistratova, E.N. et al. Thermodynamic characteristics of supramolecular complexes of aroma compounds with ordered structures of polysaccharides of corn starch and its cryotextures. Russian Chemical Bulletin 50, 300–303 (2001). https://doi.org/10.1023/A:1009546821916

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1009546821916

Navigation