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Rate Limiting Steps of Charge Transfer at Conducting Polymers

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Abstract

The rate limiting steps of the charge transfer between the solution and a conducting polymer during the switching between oxidation states are investigated by means of ac electrogravimetry. It is shown that the polymer requires anion entry and cation and solvent expulsion to compensate for the positive charges formed during the polymer oxidation. The insertion/expulsion laws, the diffusion coefficients of the species, and the atomic weights of the inserted/expelled species are determined.

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Authors and Affiliations

  1. UPR 15 CNRS “Physique des Liquides et Électrochimie”, Université Pierre et Marie Curie, Tour 22, place Jussieu 4, 75252, Paris, Cedex 05, France

    S. El Sana & H. Perrot

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  1. S. El Sana
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  2. C. Gabrielli
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  3. H. Perrot
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El Sana, S., Gabrielli, C. & Perrot, H. Rate Limiting Steps of Charge Transfer at Conducting Polymers. Russian Journal of Electrochemistry 40, 267–272 (2004). https://doi.org/10.1023/B:RUEL.0000019663.27800.9e

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  • DOI: https://doi.org/10.1023/B:RUEL.0000019663.27800.9e

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