Skip to main content
Log in

Three-Phase Flash Calculation for Hydrocarbon Systems Containing Water1

  • Published:
Theoretical Foundations of Chemical Engineering Aims and scope Submit manuscript

Abstract

This study is aimed at developing a simple and stable method for accurately calculating the three-phase compositions existing at equilibrium in VLLE region. Incorporation of a simple method for estimating initial K-values in the present algorithm allows this algorithm to more easily and accurately calculate the composition of each phase in vapor–liquid–liquid equilibrium. The old algorithms have not used the above method but used trial and error procedures (such as minimization of Gibbs free energy) which is more difficult and time consuming. Compared with the experimental data, the present method gives more reasonable results.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Shinta, A.A. and Firoozabadi, A., Equation of State Representation of Aqueous Mixtures Using an Association Model, Can. J. Chem. Eng., 1995, vol. 73.

  2. Peng, D.Y. and Robinson, D.B., Two and Three-Phase Equilibrium Calculations for Systems Containing Water, Can. J. Chem. Eng., 1976, vol. 54.

  3. Peng, D.Y. and Robinson, D.B., Two and Three-Phase Equilibrium Calculations for Coal Gasification an Related Process, ACS Symposium Series, Thermodynamics of Aqueous Systems with Industrial Applications, 1980, vol. 133.

  4. Rachford, H.H., Jr. and Rice, J.D., Procedure for Use of Electronic Digital Computers in Calculating Flash Vaporization Hydrocarbon Equilibrium, Trans. AIME, 1952, vol. 195.

  5. Wilson, G., A Modified Redich-Kwong Equation of State, Application to General Physical Data Calculation, J. AIChE, 1969.

  6. Prausnitz, J.M., Lichtenthaler, R.N., and Azevedo, E.G., Molecular Thermodynamics of Fluid-Phase Equilibria, 2nd. Edit., Prentice-Hall Inc., Englewood Cliffs; NJ, 1986, p. 142.

    Google Scholar 

  7. Anderko, A., Phase Equilibria in Aqueous Systems from an Equation of State Based on the Chemical Approach, Fliud Phase Equilibria J., 1991, vol. 65, p. 89.

    Google Scholar 

  8. Nishiumi, H. and Arai T., Generalization of the Binary Interaction Parameter of the Peng-Robinson EOS by Component Family, Fluid-Phase Equilibria J., 1988, vol. 42, p. 43.

    Google Scholar 

  9. Owens, J.L. and Wilson, G.M., Vapor-Liquid-Liquid Equilibria, K-Values, Density, and Viscosity Measurements on the Water/ Octane/ Docasane Ternary System and on the Water/Methane/Decane Ternary System, Report Presented by WiltechCo. Inc., Provo. Utah, 1986.

    Google Scholar 

  10. API, Technical Data Book, American Petroleum Institue-Division of Refining, Washington, D.C., 1970.

  11. Osborne, A., Three-phase VLLE data, Chemical Engineering Science. J., 1964, vol. 71, no. 12, p. 97.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mokhatab, S. Three-Phase Flash Calculation for Hydrocarbon Systems Containing Water1 . Theoretical Foundations of Chemical Engineering 37, 291–294 (2003). https://doi.org/10.1023/A:1024043924225

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1024043924225

Keywords

Navigation